56814-33-6

Basic information

• Product Name: Benzene, [(methoxymethyl)seleno]-
• CAS NO: 56814-33-6
• Molecular Formula: C8H10OSe
• Molecular Weight: 201.127
• Mol File: 56814-33-6.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzene, [(methoxymethyl)seleno]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(methoxymethyl)seleno]-(56814-33-6)
• EPA Substance Registry System: Benzene, [(methoxymethyl)seleno]-(56814-33-6)

Safety Data

• Hazardous Substances Data: 56814-33-6(Hazardous Substances Data)

Upstream product

• 109-87-5 Dimethoxymethane 
• 1666-13-3 diphenyl diselenide 
• 41924-21-4 phenyl tributylstannyl selenide 
• 66675-06-7 1-(methoxymethoxy)hexane 
• 645-96-5 Benzeneselenol 
• 107-30-2 chloromethyl methyl ether 
• 591-51-5 phenyllithium 
• 366006-46-4 bis(methoxymethyl) diselenide 
• 108-86-1 bromobenzene 

Downstream Products

• 16775-33-0 1-Phenyl-2-chlorethyl-(methoxyethyl)ether 
• 1666-13-3 diphenyl diselenide 
• 1312023-09-8 C₁₁H₁₃F₃O₂ 
• 1312023-10-1 C₁₂H₁₆O₃ 
• 1015081-06-7 C₉H₁₂O₃ 
• 152407-19-7 (2-Methoxyethoxy)methyl phenyl selenide 
• 1312023-07-6 2-(trimethylsilyl)ethoxymethyl phenyl selenide 
• 1312023-08-7 2-{1-[(methoxymethoxy)methyl]propyl}-1H-isoindole-1,3(2H)-dione 
• 1312023-14-5 C₉H₁₉NO₃ 
• 1312023-11-2 C₃₀H₃₆O₇ 
• 1312023-12-3 C₁₅H₂₉NO₄ 
• 1312023-15-6 C₁₁H₁₈O₄ 
• 1312023-13-4 C₁₃H₂₁NO₄S 
• 34837-55-3 Phenylselenyl bromide 

Relevant articles and documents

O-(tert-butyl) Se-phenyl selenocarbonate: A convenient, bench-stable and metal-free precursor of benzeneselenol

A study by our laboratory shows that air, light and moisture stable O-(tert-butyl) Se-phenyl selenocarbonate could be employed as a safer, practical and efficient alternative to generate “in situ” benzeneselenol or benzeneselenolate anion under different and transition metal-free conditions. This procedure seems to be of general application since the nucleophilic selenium species obtained can be trapped by electrophiles such as alkyl halides, epoxides and electron-deficient alkenes and alkynes under different reaction conditions.

Mixed acetals as new precursors for selenium electrophiles

A wide range of precursors for selenium electrophiles is already known, but the requirements for the development of polymer-bound selenium reagents are different. Herein we report mixed acetals as new precursor molecules for the synthesis of selenium electophiles under very mild reaction conditions. The use of (MeOCH2Se)2 allows a very fast access to these mixed acetals. Chiral precursor molecules can be synthesized as well and employed in efficient stereoselective selenenylation reactions.

SYNTHETIC APPLICATION OF SELENOSTANNANES: SELENOALKOXYLATION OF ACETALS

Monoselenoacetals were easily prepared from the corresponding acetals and tributyltin phenyl selenide (n-Bu3SnSePh) by the action of BF3*Et2O in fair to good yields.