56909-04-7

Basic information

• Product Name: 14-Pentadecynoic acid methyl ester
• Synonyms: 14-Pentadecynoic acid methyl ester
• CAS NO: 56909-04-7
• Molecular Formula: C₁₆H₂₈O₂
• Molecular Weight: 0
• Mol File: 56909-04-7.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 14-Pentadecynoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 14-Pentadecynoic acid methyl ester(56909-04-7)
• EPA Substance Registry System: 14-Pentadecynoic acid methyl ester(56909-04-7)

Safety Data

• Hazardous Substances Data: 56909-04-7(Hazardous Substances Data)

Upstream product

• 173074-89-0 12‐(benzyloxy)dodecanal 
• 910631-01-5 ethyl 14-hydroxytetradecanoate 
• 134834-32-5 12-(benzyloxy)dodecan-1-ol 
• 910631-00-4 (E)-14-Benzyloxy-tetradec-2-enoic acid ethyl ester 
• 101434-22-4 ethyl 14-oxotetradecanoate 
• 67-56-1 methanol 
• 90965-06-3 dimethyl 1-(1-diazo-2-oxopropyl)phosphonate 

Downstream Products

• 910630-80-7 C₇₉H₁₁₃NO₁₁Si 
• 910630-95-4 C₇₉H₁₁₃NO₁₁Si 
• 910630-86-3 (17R,18S,19S,20S,21S,22S)-18,19,20,21,22-Pentakis-benzyloxy-25-((S)-1-tert-butoxycarbonyl-2-methyl-propylcarbamoyl)-17-hydroxy-pentacos-14-ynoic acid 
• 910630-96-5 (17R,18S,19S,20S,21S,22S)-18,19,20,21,22-Pentakis-benzyloxy-25-((R)-1-tert-butoxycarbonyl-2-methyl-propylcarbamoyl)-17-hydroxy-pentacos-14-ynoic acid 
• 212913-84-3 Pentadec-14-in-saeure 

Relevant articles and documents

Stereochemistry of sagittamide A: Prediction and confirmation

The C5-C10 relative stereochemistry of sagittamide A was predicted, with the use of the 3JH,H profiles assembled from the spin-coupling constants reported in the literature. The predicted relative stereochemistry was then confirmed by a total synthesis of two relevant remote diastereomers. The absolute configuration of sagittamide A was established through a detailed 1H NMR analysis of the two remote diastereomers, followed by doping experiments of them with the authentic natural product.