56954-91-7

Basic information

• Product Name: 9H-Fluorene-9-methanol, a-phenyl-
• CAS NO: 56954-91-7
• Molecular Formula: C20H16O
• Molecular Weight: 272.346
• Mol File: 56954-91-7.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 9H-Fluorene-9-methanol, a-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 9H-Fluorene-9-methanol, a-phenyl-(56954-91-7)
• EPA Substance Registry System: 9H-Fluorene-9-methanol, a-phenyl-(56954-91-7)

Safety Data

• Hazardous Substances Data: 56954-91-7(Hazardous Substances Data)

Upstream product

• 1940-57-4 9H-fluoren-9-yl bromide 
• 100-52-7 benzaldehyde 
• 67-56-1 methanol 
• 49670-33-9 9-(hydroxy-phenyl-methyl)-9H-fluoren-9-ol 
• 881-04-9 9H-fluoren-9-yllithium 
• 7385-10-6 9-(trimethylsilyl)fluorene 
• 7351-45-3 9,9'-bis(trimethylsilyl)fluorene 
• 86-73-7 9H-fluorene 
• 1603-73-2 fluoren-9-yl-phenyl ketone 
• 62731-48-0 (9H-fluorene-9,9-diyl)bis(phenylmethanone) 
• 85055-89-6 benzoic acid-(fluoren-9-yl-phenyl-methyl ester) 
• 124-41-4 sodium methylate 
• 63839-89-4 Acetoxy-(9-fluorenyl)-phenyl-methan 

Downstream Products

• 85055-89-6 benzoic acid-(fluoren-9-yl-phenyl-methyl ester) 
• 1836-87-9 9-Benzylidene-9H-fluorene 

Relevant articles and documents

An N-heterocyclic carbene-catalyzed switchable reaction of 9-(trimethylsilyl)fluorene and aldehydes: Chemoselective synthesis of dibenzofulvenes and fluorenyl alcohols

An N-heterocyclic carbene-catalyzed synthesis of dibenzofulvenes and fluorenyl alcohols was developed. In the presence of 10 mol% NHC (1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) and 4 ? molecular sieves, 9-(trimethylsilyl)fluorene undergoes an olef

Photochemical Pinacol Rearrangements of Unsymmetrical Diols

The photochemical pinacol reaction of a series of nonsymmetrical 9-fluorenyl-substituted vic-diols was investigated and compared with their acid-catalyzed thermal reaction. Unlike the thermal reaction, the radiation-induced processes involve only fluorenyl cations, as is reflected in differences of product distribution between the two reactions. From the product studies, substituent migratory aptitudes are reversed in the photochemical process, suggesting that kinetic control takes place under neutral conditions unlike the acid-catalyzed thermal reactions. The presence of fluorenyl cation intermediates and their lifetimes were established by laser flash spectroscopy studies.

CATALYTIC ACTIVITY OF TETRABUTYLAMMONIUM FLUORIDE ON DIFFERENT CARRIERS IN REACTIONS OF FLUORENE AND ITS DERIVATIVES WITH BENZALDEHYDE

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