56956-46-8Relevant articles and documents
Preparation of 1,2-Dienes by the Palladium-Catalyzed Hydrogenolysis of 3-Methoxycarbonyloxy-1-alkynes with Ammonium Formate
Tsuji, Jiro,Sugiura, Teruo,Minami, Ichiro
, p. 603 - 606 (2007/10/02)
A useful preparative method for 1,2-dienes from 3-methoxycarbonyloxy-1-alkynes by the palladium-catalyzed hydrogenolysis with ammonium formate is described. 3-Methoxycarbonyloxy-1-alkynes are prepared by the addition of magnesium acetylide to ketones or aldehydes, followed by quenching with methyl chloroformate.
The Reaction of 2-Alkyl-1,1-dichlorocyclopropanes with Lithium Naphtalene
Watanabe, Shoji,Fujita, Tsutomu,Suga, Kyoichi,Kasahara, Kaoru
, p. 1161 - 1165 (2007/10/02)
2-Alkyl-1,1-dichlorocyclopropanes react with lithium naphthalene to give a mixture of dechlorinated alkylcyclopropanes and unsaturated hydrocarbons.For example, a mixture of octylcyclopropane and undec-1-yne was obtained from the reaction of 1,1-dichloro-2-octylcyclopropane and lithium naphthalene.