571167-64-1Relevant articles and documents
Galactose-Grafted 2D Nanosheets from the Self-Assembly of Amphiphilic Janus Dendrimers for the Capture and Agglutination of Escherichia coli
Atchimnaidu, Siriki,Golla, Murali,Harikrishnan, Kaloor S.,Kalathil, Jemshiya,Krishna, Jithu,Krishnan, Nithiyanandan,Kumar, Nilima Manoj,Perumal, Devanathan,Varghese, Reji,Vijayan, Dileep K.
, (2020)
High aspect ratio, sugar-decorated 2D nanosheets are ideal candidates for the capture and agglutination of bacteria. Herein, the design and synthesis of two carbohydrate-based Janus amphiphiles that spontaneously self-assemble into high aspect ratio 2D sh
Chemical surface modification of self-assembled monolayers by radical nitroxide exchange reactions
Wagner, Hendrik,Brinks, Marion K.,Hirtz, Michael,Schaefer, Andreas,Chi, Lifeng,Studer, Armido
supporting information; experimental part, p. 9107 - 9112 (2011/10/01)
This article describes the application of nitroxide exchange reactions of surface-bound alkoxyamines as a tool for reversible chemical modification of self-assembled monolayers (SAMs). This approach is based on radical chemistry, which allows for introduction of various functional groups and can be used to reversibly introduce functionalities at surfaces. To investigate the scope of this surface chemistry, alkoxyamines with different functionalities were synthesized and were then applied to the immobilization of, for example, dyes, sugars, or biotin. Surface analysis was carried out by contact angle, X-ray photoelectron spectroscopy, and fluorescence microscopy measurements. The results show that this reaction is highly efficient, reversible, and mild and allows for immobilization of various sensitive functional groups. In addition, Langmuir-Blodgett lithography was used to generate structured SAMs. Site-selective immobilization of a fluorescent dye could be achieved by nitroxide exchange reactions. A radical exchange: Chemical modification of silicon surfaces with alkoxyamine-based self-assembled monolayers (SAMs) was achieved by reversible radical nitroxide exchange reactions.
Synthesis of copolymers alternating oligophenylenevinylene subunits and fullerene moieties
Gutiérrez-Nava, Manuel,Masson, Patrick,Nierengarten, Jean-Fran?ois
, p. 4487 - 4490 (2007/10/03)
Linear polymers alternating oligophenylenevinylene (OPV) moieties and C60 subunits have been prepared in good yields by polycondensation of a bifunctional fullerene derivative with an OPV monomer bearing two alcohol functions. These polymers ha