57432-86-7

Basic information

• Product Name: Benzene, [(3,3-diethoxypropyl)thio]-
• CAS NO: 57432-86-7
• Molecular Formula: C13H20O2S
• Molecular Weight: 240.367
• Mol File: 57432-86-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, [(3,3-diethoxypropyl)thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(3,3-diethoxypropyl)thio]-(57432-86-7)
• EPA Substance Registry System: Benzene, [(3,3-diethoxypropyl)thio]-(57432-86-7)

Safety Data

• Hazardous Substances Data: 57432-86-7(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 27098-65-3 3-phenylsulfanyl-propionaldehyde 
• 122-51-0 orthoformic acid triethyl ester 
• 149-73-5 trimethyl orthoformate 
• 59067-07-1 3-bromopropinaldehyde diethyl acetal 
• 13133-62-5 thiophenolate 
• 35573-93-4 3-chloro-1,1-diethoxy-propane 

Downstream Products

• 92963-71-8 2-(2-benzenesulfinyl-ethyl)-2,3-dihydro-benzo[e][1,3]oxazin-4-one 
• 92963-99-0 2-(2-benzenesulfonyl-ethyl)-2,3-dihydro-benzo[e][1,3]oxazin-4-one 
• 57398-32-0 C₂₀H₂₆O₄S 
• 57398-31-9 (1,1-Diethoxy-nonane-3-sulfonyl)-benzene 
• 57398-39-7 (1,1-Diethoxy-3,4-dimethyl-pentane-3-sulfonyl)-benzene 
• 57398-33-1 (1,1-Diethoxy-4-methyl-pentane-3-sulfonyl)-benzene 
• 57398-45-5 3-Benzenesulfonyl-nonanal 
• 57398-46-6 3-Benzenesulfonyl-4-phenyl-butyraldehyde 
• 57398-47-7 3-Benzenesulfonyl-4-methyl-pentanal 
• 53356-85-7 (4,4-diethoxybutyl)benzene 
• 53305-11-6 1,1-diethoxy-4-methyl-pentane 
• 54815-13-3 pelargonaldehyde diethyl acetal 
• 86531-05-7 (E)-1-methoxy-3-<(phenylthio)methyl>-1,3-butadiene 
• 86531-33-1 (Z)-1-methoxy-3-<(phenylthio)methyl>-1,3-butadiene 

Relevant articles and documents

Baker's yeast mediated biohydrogenation of sulphur-functionalised methacrolein derivatives. Stereochemical aspects of the reaction and preparation of the two enantiomers of useful C4 bifunctional chiral synthons

The baker's yeast mediated reduction of sulphur-functionalised methacroleins 11, 15 and 18 leads to the preparation of the bifunctional methyl branched C4 chiral synthons 6 and 7. The stereochemical aspects of the biohydrogenation have been investigated. Both the oxidation state of sulphur and the isomeric position of the double bond affected the enantioselectivity of the reduction strongly, thus, offering access to the two enantiomeric forms of 6 and 7.

SYNTHESIS OF FUNCTIONALIZED ISOPRENES INVOLVING A TERMINAL ALKOXY GROUP AND THEIR HIGHLY REGIOSELECTIVE DIELS-ALDER REACTION

Functionalized isoprenes involving a terminal alkoxy group are newly synthesized, and a highly regioselective Diels-Alder reaction of these dienes with various unsymmetric dienophiles is described.