57542-89-9Relevant articles and documents
Tuning of the structures of chiral phosphane-phosphites: Application to the highly enantioselective synthesis of α-acyloxy phosphonates by catalytic hydrogenation
Rubio, Miguel,Vargas, Sergio,Suarez, Andres,Alvarez, Eleuterio,Pizzano, Antonio
, p. 1821 - 1833 (2008/02/04)
A family of new chiral phosphane-phosphites 5 has been prepared and employed in the synthesis of rhodium complexes of formulation [Rh(cod)(5)]BF4 (7). The use of bulky phosphane or phosphite groups in the preparation of 7 avoids the formation of undesired