57601-36-2

Basic information

• Product Name: 2-(3-acetyl-3-methyltriaz-1-en-1-yl)benzoic acid
• CAS NO: 57601-36-2
• Molecular Weight: 221.216
• Mol File: 57601-36-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(3-acetyl-3-methyltriaz-1-en-1-yl)benzoic acid(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(3-acetyl-3-methyltriaz-1-en-1-yl)benzoic acid(57601-36-2)
• EPA Substance Registry System: 2-(3-acetyl-3-methyltriaz-1-en-1-yl)benzoic acid(57601-36-2)

Safety Data

• Hazardous Substances Data: 57601-36-2(Hazardous Substances Data)

Upstream product

• 5344-90-1 2-Aminobenzyl alcohol 
• 1610366-30-7 C₈H₁₁N₃O 

Downstream Products

• 80335-44-0 N-methyl-N-phenyl-(o-phenylthio)aniline 
• 80335-45-1 C₁₉H₁₆⁽²⁾HNS 
• 883-39-6 1-phenyl-1H-benzotriazole 
• 4953-10-0 1-(4-methoxyphenyl)-1H-benzo[d][1,2,3]triazole 
• 1579942-26-9 4-(tert-butyl)benzyl 2-(1H-benzo[d][1,2,3]triazol-1-yl)acetate 
• 69218-46-8 ethyl (1H-benzotriazol-1-yl)acetate 
• 171193-30-9 1-(γ-phenylallyl)benzotriazole 
• 17626-88-9 2-(tert-butyl)benzo[d]thiazole 

Relevant articles and documents

A photoinduced, benzyne click reaction

The [3 + 2] cycloaddition of azides and alkynes has proven invaluable across numerous scientific disciplines for imaging, cross-linking, and site-specific labeling among many other applications. We have developed a photoinitiated, benzyne-based [3 + 2] cycloaddition that is tolerant of a variety of functional groups as well as polar, protic solvents. The reaction is complete on the minute time scale using a single equivalent of partner azide, and the benzyne photoprecursor is stable for months under ambient light at room tempurature. Herein we report the optimization and scope of the photoinitiated reaction as well as characterization of the cycloaddition products.