57639-92-6

Basic information

• Product Name: Mn(CO)4Br{Sb(C₆H₅)3}
• CAS NO: 57639-92-6
• Molecular Weight: 599.951
• Mol File: 57639-92-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Mn(CO)4Br{Sb(C₆H₅)3}(CAS DataBase Reference)
• NIST Chemistry Reference: Mn(CO)4Br{Sb(C₆H₅)3}(57639-92-6)
• EPA Substance Registry System: Mn(CO)4Br{Sb(C₆H₅)3}(57639-92-6)

Safety Data

• Hazardous Substances Data: 57639-92-6(Hazardous Substances Data)

Upstream product

• 14516-54-2 bromopentacarbonylmanganese(I) 
• 603-36-1 triphenylantimony 

Relevant articles and documents

Metal carbonyls. V. Kinetics of the reaction of monosubstituted manganese pentacarbonyl bromides with a variety of reagents

The rates of reaction of Mn(CO)4LX with a variety of reagents L′ to form Mn(CO)3LL′X were found to be independent of the nature and concentration of L′, but to decrease with increasing atomic number of X and also to decrease with changes in L in the following order: P(C6H5)3 > As(C6H5)3 > P(C4H9)3 ～ P(C6H5)2Cl > P(OC6H5)3 ～ Sb(C6H5)3 > P(C6H5)Cl2 ～ P(OC4H9)3 > P(OCH2)3CCH3 (the group C4H9 is n-butyl). These results have been interpreted as indicating a dissociation mechanism in which the bulkiness of L determines the rate of CO dissociation. The absorption maxima of several Mn(CO)4LBr complexes in the near-ultraviolet region also are reported.