57646-22-7Relevant articles and documents
Proton or Carbene Transfer? On the Dark and Light Reaction of Diazoalkanes with Alcohols
Empel, Claire,He, Feifei,Jana, Sripati,Koenigs, Rene M.,Pei, Chao
, (2022/02/21)
The formal alkylation reaction of OH groups with diazoalkanes under catalyst-free reaction conditions finds broad application in organic synthesis. However, even today, this reaction is mainly limited to the use of diazomethane as reaction partner. In thi
Why are vinyl cations sluggish electrophiles?
Byrne, Peter A.,Kobayashi, Shinjiro,Würthwein, Ernst-Urich,Ammer, Johannes,Mayr, Herbert
, p. 1499 - 1511 (2017/02/10)
The kinetics of the reactions of the vinyl cations 2 [Ph2C=C+-(4-MeO-C6H4)] and 3 [Me2C=C+-(4-MeO-C6H4)] (generated by laser flash photolysis) with diverse nucleophile
Boron Trifluoride?Diethyl Ether-Catalyzed Etherification of Alcohols: A Metal-Free Pathway to Diphenylmethyl Ethers
Li, Jiaqiang,Zhang, Xiaohui,Shen, Hang,Liu, Qing,Pan, Jing,Hu, Wen,Xiong, Yan,Chen, Changguo
, p. 3115 - 3120 (2015/11/03)
A novel boron trifluoride?diethyl ether (BF3?OEt2)-catalyzed etherification procedure has been developed in which primary and secondary alcohols are easily converted into diphenylmethyl ethers with yields of up to 99%.