5773-37-5

Basic information

• Product Name: 4,4-dimethyl-1-cyclohexene acetate
• Synonyms: 4,4-dimethyl-1-cyclohexene acetate
• CAS NO: 5773-37-5
• Molecular Weight: 152.236
• Mol File: 5773-37-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 4,4-dimethyl-1-cyclohexene acetate(CAS DataBase Reference)
• NIST Chemistry Reference: 4,4-dimethyl-1-cyclohexene acetate(5773-37-5)
• EPA Substance Registry System: 4,4-dimethyl-1-cyclohexene acetate(5773-37-5)

Safety Data

• Hazardous Substances Data: 5773-37-5(Hazardous Substances Data)

Upstream product

• 72429-03-9 N-(3,7-dimethyl-octa-2,6-dienylidene)-aniline 
• 4255-62-3 4,4-dimethylcyclohexane-1-one 
• 74-86-2 acetylene 
• 55504-11-5 4,4-dimethyl-1-trimethylsilylcyclohexene 
• 75-36-5 acetyl chloride 
• 55504-16-0 1-chloro-4,4-dimethylcyclohexene 
• 40267-53-6 (E)-N,N-diethyl-3,7-dimethyl-2,6-octadienylamine 
• 57784-08-4 N,N-diethyl(3,7-dimethylocta-cis-2,6-dien-1-yl)amine N-oxide 
• 1066-54-2 trimethylsilylacetylene 

Downstream Products

• 18325-78-5 1-(1-Hydroxy-ethyl)-4,4-dimethyl-cyclohexen 
• 79-20-9 acetic acid methyl ester 

Relevant articles and documents

Access to Cycloalkeno[ c]-Fused Pyridines via Pd-Catalyzed C(sp2)-H Activation and Cyclization of N-Acetyl Hydrazones of Acylcycloalkenes with Vinyl Azides

A novel Pd(II)-catalyzed vinylic C-H activation and cyclization has been developed, reacting a series of small, medium, and large N-acetyl hydrazones of acylcycloalkenes with vinyl azides to access diverse cycloalkeno[c]-fused pyridine scaffolds. This protocol provides progress in C(sp2)-H bond activation of medium to large cycloalkenes, and the target products can be obtained in a specific regioselectivity with good functional group tolerance and a broad substrate scope.

Friedel-Crafts Reactions of Some Vinyisilanes

Substituted cyclohexenylsilanes (2), (5), (9), and (13) undergo Friedel-Crafts reactions to give substitution products, site-selectively at the carbon atom carrying the trimethylsilyl group. β-Trimethylsilylstyrene (17) similary gives more substitution in Friedel-Crafts reactions with benzoyl chloride and with phenylacetyl chloride than styrene itself.The syntheses of the silanes are reported, and some limitations of the idea identified.