57757-66-1Relevant articles and documents
Preparation and chromatographic evaluation of columns for reversed-phase liquid chromatography
Zhang, Mengyao,Wang, Haibo,Chen, Hui,Sun, Xiaoli,Jiang, Ru
experimental part, p. 60 - 68 (2012/05/07)
Column selection in reversed-phase liquid chromatography is still not a straightforward process. In this study, we have evaluated and compared the performance of several traditional C18 phases with polar-modified phases and found distinct differences in the chromatographic behavior between two groups, as well as a high degree of variability within each group. The polar-endcapped phases exhibit similar hydrophobic selectivity, higher hydrogen bonding capacities and silanol activity with reference to the conventional C18 columns. The polar-embedded phases displayed a greatly reduced hydrophobic nature and a significantly reduced silanol activity compared to the conventional C18 phases. It appears that ionic and/or dipole interactions play a significant role in the overall retention behavior of the polar-modified phases towards basic and acidic analytes.
PROCESS FOR PRODUCING ORGANOALKOXYSILANES FROM ORGANIC ACIDS OR CYANATES AND HALOALKYLALKOXYSILANES
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Page/Page column 5, (2010/11/25)
A process for the preparation of organoalkoxysilanes containing one or more organic functional groups derived from organic acids or hydrogen cyanates, by a continuous or batch process utilizing a solid guanidinium salt as a phase transfer catalyst for the reaction between a liquid phase haloalkylalkoxysilane and a solid phase alkali or alkaline earth metal salt or ammonium salt of an organic acid or a metal cyanate.