57774-14-8

Basic information

• Product Name: meso-Tetrakis(4-chlorophenyl)porphyrin-Ni(II)
• Synonyms: meso-Tetrakis(4-chlorophenyl)porphyrin-Ni(II);Ni-(5,10,15,20-tetra-(p-chlorophenyl)porphyrin), 97%
• CAS NO: 57774-14-8
• Molecular Formula: C₄₄H₂₄Cl₄N₄Ni
• Molecular Weight: 809.2
• Product Categories: MOFS COFS
• Mol File: 57774-14-8.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: meso-Tetrakis(4-chlorophenyl)porphyrin-Ni(II)(CAS DataBase Reference)
• NIST Chemistry Reference: meso-Tetrakis(4-chlorophenyl)porphyrin-Ni(II)(57774-14-8)
• EPA Substance Registry System: meso-Tetrakis(4-chlorophenyl)porphyrin-Ni(II)(57774-14-8)

Safety Data

• Hazardous Substances Data: 57774-14-8(Hazardous Substances Data)

Usage

General Description

Meso-Tetrakis(4-chlorophenyl)porphyrin-Ni(II) is a chemical compound that consists of a central nickel ion coordinated with four molecules of 4-chlorophenylporphyrin. Porphyrins are a group of organic compounds known for their distinct ring structure, and they are commonly found in biological systems as components of heme proteins. The nickel ion in this compound is bound to the nitrogen atoms in the porphyrin rings, forming a stable coordination complex. Meso-Tetrakis(4-chlorophenyl)porphyrin-Ni(II) is often used as a catalyst in various chemical reactions, and it has potential applications in areas such as organic synthesis and photodynamic therapy. It is also studied for its potential use in sensor and electronic device applications due to its unique electronic and optical properties.

Upstream product

• 22112-77-2 5,10,15,20-tetra-(4-chlorophenyl)porphyrin 
• 373-02-4 nickel diacetate 
• 109-97-7 pyrrole 
• 104-88-1 4-chlorobenzaldehyde 
• 3264-82-2 nickel(II) acetylacetonate 

Downstream Products

• 88669-49-2 (5,10,15,20-tetrakis(p-chlorophenyl)porphinato)nickel(II)⁽¹⁺⁾ 
• 88669-53-8 (5,10,15,20-tetrakis(p-chlorophenyl)porphinato)nickel(II)^(1-) 

Relevant articles and documents

Structural, photophysical and theoretical studies of two dodecachlorinated porphyrins

Two dodecachlorinated porphyrins, 2,3,7,8,12,13,17,18-octachloro-5,10,15, 20-tetra(4-chlorophenyl)porphyrin free base (TCl12PPH2) and its nickel compound (TCl12PPNi), have been synthesized. Single-crystal X-ray diffraction

Synthesis method of tetraaryl nickel porphyrin catalyzed by anhydrous aluminum trichloride

The invention discloses a synthesis method of tetraaryl nickel porphyrin catalyzed by anhydrous aluminum trichloride, which comprises the following step: refluxing aromatic aldehyde, pyrrole and nickel salt in a DMF solvent under the catalysis of anhydrous aluminum trichloride to synthesize tetraaryl nickel porphyrin in one step. The reaction process comprises the following steps: sequentially adding anhydrous aluminum trichloride, aryl aldehyde, pyrrole and nickel salt into DMF (Dimethyl Formamide) while stirring, stopping the reaction after heating reflux reaction for a certain time, cooling, standing overnight near 273K, and carrying out suction filtration to obtain a nickel porphyrin crystal. According to the method, aromatic aldehyde, pyrrole and nickel salt are directly used as raw materials, porphin is not needed, strongly corrosive organic acid is not used as a solvent, high-purity tetraaryl nickel porphyrin is obtained at a high yield under the condition that a complex separation means is not needed, and industrial production is easy to achieve.

Synthesis of calix[3]dipyrrins by a modified Lindsey protocol

(Figure Presented) Bowled over: Calix[3]dipyrrins were synthesized from pyrrole and aryl aldehyde precursors by the Lindsey protocol, modified by the presence of a small amount of water. These bowl-shaped macrocycles can accommodate three metal (M) ions such as NiII and CuII in a hexagonal M3O3 manner (see structure; Cu green, N blue, O red, C black).