57825-90-8

Basic information

• Product Name: cis-2-Benzyl-2-oxo-4-methyl-1,3,2-dioxaphosphorinan
• CAS NO: 57825-90-8
• Molecular Weight: 226.212
• Mol File: 57825-90-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cis-2-Benzyl-2-oxo-4-methyl-1,3,2-dioxaphosphorinan(CAS DataBase Reference)
• NIST Chemistry Reference: cis-2-Benzyl-2-oxo-4-methyl-1,3,2-dioxaphosphorinan(57825-90-8)
• EPA Substance Registry System: cis-2-Benzyl-2-oxo-4-methyl-1,3,2-dioxaphosphorinan(57825-90-8)

Safety Data

• Hazardous Substances Data: 57825-90-8(Hazardous Substances Data)

Upstream product

• 57825-93-1 trans-2-Benzyl-2-seleno-4-methyl-1,3,2-dioxaphosphorinan 
• 16368-20-0 cis-2-hydro-2-oxo-4-methyl-1,3,2-dioxaphosphorinane 
• 100-44-7 benzyl chloride 
• 16368-20-0 trans-4-methyl-1,3,2-dioxaphosphorinane 2-oxide 
• 57825-92-0 trans-2-benzyl-4-methyl-[1,3,2]dioxaphosphinane 

Relevant articles and documents

Stereospecificity of alkylation of phosphite anion in electrochemical version of the Michaelis - Becker reaction

Benzylation of cis-2-hydro-2-oxo-4-methyl-1,3,2-dioxaphosphorinane in the electrochemical version of the Michaelis - Becker reaction occurs stereospecifically with retention of the stereochemistry of the hydrophosphoryl center and affords stereochemically pure 2-benzyl-2-oxo-4-methyl-1,3,2-dioxaphosphorinane (yield 60-70 %). The structure of this compound was determined by X-ray diffraction analysis. The mechanism of the process was discussed.