57902-11-1Relevant articles and documents
Reactions of 1,4-dinitroimidazoles with hydrazines
Suwinski, Jerzy,Szczepankiewicz, Wojciech,Holt, Elizabeth M.
, p. 14905 - 14916 (2007/10/03)
Reaction of 2-methyl-1,4-dinitroimidazole with hydrazine results in expansion of the imidazole ring and formation of the 1.2.4-triazine derivative. Reaction of 1,4-dinitroimidazole with N-aminomorpholine yields 1-(N-morpholino)-4-nitroimidazole, by degenerative transformation of the imidazole ring. Treatment of 1,4-dinitroimidazoles with t-butoxycarbonylhydrazine results in the break down of the imidazole ring and formation of glyoxal dihydrazone derivatives. Structures of representative heterocyclic products were determined by X-ray analysis.