579472-58-5Relevant articles and documents
Selective arylation at the vinylic site of cyclic olefins
Wu, Xiaojin,Zhou, Jianrong
supporting information, p. 4794 - 4796 (2013/06/05)
Cyclic olefins usually give Heck products having an aryl ring residing at the allylic or homoallylic position. We describe herein a new method that allows arylation at the vinylic position of various cyclic olefins.
Process of heterocoupling by electrolytic microbattery, use of cobalt for implementing said coupling and composition for doing so
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Page 14, (2008/06/13)
This invention has as its object a process for preparation of vinyl aryl derivatives by an electrochemical path. This process is defined in that it consists in subjecting a composition that comprises a cobalt salt, an aromatic halide and a vinyl ester to the action of a metal that is at least as reducing as zinc. Application to organic synthesis.