5798-76-5

Basic information

• Product Name: Benzoic acid, 4-broMo-, phenyl ester
• Synonyms: Benzoic acid, 4-broMo-, phenyl ester
• CAS NO: 5798-76-5
• Molecular Formula: C₁₃H₉BrO₂
• Molecular Weight: 277.11336
• Mol File: 5798-76-5.mol
• Article Data: 35

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzoic acid, 4-broMo-, phenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 4-broMo-, phenyl ester(5798-76-5)
• EPA Substance Registry System: Benzoic acid, 4-broMo-, phenyl ester(5798-76-5)

Safety Data

• Hazardous Substances Data: 5798-76-5(Hazardous Substances Data)

Upstream product

• 201230-82-2 carbon monoxide 
• 589-87-7 1,4-bromoiodobenzene 
• 108-95-2 phenol 
• 586-76-5 4-Bromobenzoic acid 
• 2996-92-1 phenyl trimethylsiloxane 
• 1242438-10-3 O-(4-bromophenyl) O-phenyl thiocarbonate 
• 98-80-6 phenylboronic acid 
• 99-90-1 para-bromoacetophenone 
• 586-75-4 4-chlorobenzoyl chloride 
• 50-00-0 formaldehyd 
• 622-88-8 4-bromophenylhydrazine hydrochloride 
• 38469-37-3 bis(4-bromobenzoyloxy)iodobenzene 
• 71-43-2 benzene 
• 66003-76-7 Diphenyliodonium triflate 

Downstream Products

• 5933-32-4 4-bromobenzoic acid hydrazide 
• 866849-59-4 phenyl 4-(3-phenoxyprop-1-ynyl)benzoate 
• 760990-49-6 2-(4-bromobenzoyl)-5,6-dimethoxy-indan-1-one 
• 760994-54-5 6-(benzyloxy)-2-(4-bromobenzoyl)-5-methoxyindan-1-one 
• 760990-50-9 C₁₈H₁₅BrN₂O₂ 
• 760994-55-6 7-(benzyloxy)-3-(4-bromophenyl)-6-methoxy-1,4-dihydroindeno[1,2-c]pyrazole 

Relevant articles and documents

Acetyl nitrate mediated conversion of methyl ketones to diverse carboxylic acid derivatives

The development of a novel acetyl nitrate mediated oxidative conversion of methyl ketones to carboxylic acid derivatives is described. By analogy to the haloform reaction and supported by experimental and computational investigation we propose a mechanism for this transformation.

Conversion of esters to thioesters under mild conditions

We report conversion of esters to thioestersviaselective C-O bond cleavage/weak C-S bond formation under transition-metal-free conditions. The method is notable for a general and practical transition-metal-free system, broad substrate scope and excellent functional group tolerance. The strategy was successfully deployed in late-stage thioesterification, site-selective cross-coupling/thioesterification/decarbonylation and easy-to-handle gram scale thioesterification. Selectivity and computational studies were performed to gain insight into the formation of weak C-S bonds by C-O bond cleavage, which contrasts with the traditional trend of nucleophilic additions to carboxylic acid derivatives.

Method for preparing diaryl ester compound through efficient catalysis of pyridine palladium

The invention discloses a method for preparing a diaryl ester compound through efficient catalysis of pyridine palladium. The method is used for high-efficiency high-yield preparation of the diaryl ester compound under mild conditions by taking a phenol compound, an iodobenzene compound and carbon monoxide as raw materials, triethylamine as alkali and pyridine palladium as a catalyst. The method provided by the invention has the advantages of less usage amount of the palladium catalyst, high catalytic activity of the palladium catalyst, stability of the palladium catalyst to air, simple operation, short reaction time and high atom economy, opens up a low-cost, green and efficient way for preparation of diaryl ester compounds, and has broad application prospects.