58050-49-0

Basic information

• Product Name: N-(Morpholinomethyl)carbamic acid ethyl ester
• Synonyms: N-(Morpholinomethyl)carbamic acid ethyl ester
• CAS NO: 58050-49-0
• Molecular Formula: C₈H₁₆N₂O₃
• Molecular Weight: 188.26
• Mol File: 58050-49-0.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 323.23°C (rough estimate)
• Flash Point: 132.2°C
• Appearance: /
• Density: 1.1793 (rough estimate)
• Vapor Pressure: 0.00157mmHg at 25°C
• Refractive Index: 1.4500 (estimate)
• CAS DataBase Reference: N-(Morpholinomethyl)carbamic acid ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: N-(Morpholinomethyl)carbamic acid ethyl ester(58050-49-0)
• EPA Substance Registry System: N-(Morpholinomethyl)carbamic acid ethyl ester(58050-49-0)

Safety Data

• Hazardous Substances Data: 58050-49-0(Hazardous Substances Data)

Usage

InChI:InChI=1/C8H16N2O3/c1-2-13-8(11)9-7-10-3-5-12-6-4-10/h2-7H2,1H3,(H,9,11)

Upstream product

• 109-02-4 4-methyl-morpholine 
• 817-87-8 ethyl azidocarbonate 

Relevant articles and documents

Reaction of Ethyl Azidoformate with Morpholines

Ethyl azidoformate (1) reacts rapidly with morpholine to give morpholinium azide and 4-(ethoxycarbonyl)morpholine in good yields.With 4-methylmorpholine (3), however, the azide 1 reacts at 115 deg C with evolution of nitrogen to give formal nitrene-insertion products, 4-methyl-3-(ethoxycarbonylamino)morpholine and 4-(ethoxycarbonylaminomethyl)morpholine.There has not been found any product which might arise from the nitrene-insertion into C-H bond adjacent of oxygen of 3.These results can be accounted for on the basis of the n-donor abilities of heteroatoms, O and N.