58143-70-7

Basic information

• Product Name: Benzeneacetonitrile, a-(2-methyl-2-propenyl)-
• CAS NO: 58143-70-7
• Molecular Formula: C12H13N
• Molecular Weight: 171.242
• Mol File: 58143-70-7.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Benzeneacetonitrile, a-(2-methyl-2-propenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzeneacetonitrile, a-(2-methyl-2-propenyl)-(58143-70-7)
• EPA Substance Registry System: Benzeneacetonitrile, a-(2-methyl-2-propenyl)-(58143-70-7)

Safety Data

• Hazardous Substances Data: 58143-70-7(Hazardous Substances Data)

Upstream product

• 140-29-4 phenylacetonitrile 
• 563-47-3 3-Chloro-2-methylpropene 
• 917-54-4 methyllithium 
• 137040-93-8 4-Brom-2-phenyl-4-pentennitril 
• 5798-79-8 bromo-phenyl-acetonitrile 
• 1458-98-6 2-methyl-3-bromo-1-propene 

Downstream Products

• 91562-53-7 β-Methallyl-β-phenylethylamin 
• 1314894-45-5 C₂₈H₂₉N₃O 
• 1314894-36-4 C₁₈H₂₇NSi 
• 20215-56-9 5,5-dimethyl-3-phenyldihydrofuran-2(3H)-one 
• 58143-97-8 4-(2-Methyl-allyl)-4-phenyl-cyclohex-2-enol 
• 58143-73-0 4-(2'-Methylallyl)-4-phenylcyclohex-2-en-1-on 
• 58143-72-9 4-methyl-2-phenylpent-4-enal 

Relevant articles and documents

Lanthanide-Catalyzed Tandem Addition of Amines to Cyanoalkenes: Synthesis of Cyclic Amidines

A tandem insertion of aliphatic nitriles and unactivated alkenes to the N-H bond of secondary aliphatic amines catalyzed by simple trialkyl rare-earth metal complexes was disclosed. This reaction provides a highly atom-economic and stereoselective way to a range of cyclic amidines under mild reaction conditions.

A new synthesis of pyrrolidines by way of an enantioselective Mannich/diastereoselective hydroamination reaction sequence

A new two-step synthesis of highly substituted pyrrolidines has been developed. Chiral silane Lewis acid promoted enantioselective Mannich reactions of silyl ketene imines with acylhydrazones may be used to access bishomoallylic benzoic hydrazides that in

Alkyliron and Alkylcobalt Reagents, IV.- High Superiority of Me4CoLi2 and Me4FeLi2 in Comparison to Me2CuLi and Me4MnLi2 in Cross Coupling Reactions with Vinyl Bromides

The complexes Me4MLi2 (M = Co, Fe, Mn) and Me2CuLi (prepared in situ, but well-known in isolated form) were treated with a series of vinyl bromides.In nearly all cases Me4CoLi2 and Me4FeLi2 proved to by far the best methylating reagents (high yields, reaction at -78 deg C, short reaction time, no excess of the reagent necessary.These reagents will tolerate a hydroxy or cyano group in the substrate, whereas the classical reagent for methylation of vinyl bromides, Me2CuLi, is strongly inhibited by these groups.With the methylation of hydroxyvinyl bromides a new method was found for the synthesis of allyl alcohols. Key Words: Organocobalt complexes / Organoiron complexes