58188-49-1

Basic information

• Product Name: Ni(II) tetrakis(4-nitrophenyl)porphyrin
• Synonyms: Ni(II) tetrakis(4-nitrophenyl)porphyrin
• CAS NO: 58188-49-1
• Molecular Weight: 851.413
• Mol File: 58188-49-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Ni(II) tetrakis(4-nitrophenyl)porphyrin(CAS DataBase Reference)
• NIST Chemistry Reference: Ni(II) tetrakis(4-nitrophenyl)porphyrin(58188-49-1)
• EPA Substance Registry System: Ni(II) tetrakis(4-nitrophenyl)porphyrin(58188-49-1)

Safety Data

• Hazardous Substances Data: 58188-49-1(Hazardous Substances Data)

Upstream product

• 109-97-7 pyrrole 
• 373-02-4 nickel diacetate 
• 555-16-8 4-nitrobenzaldehdye 
• 3264-82-2 nickel(II) acetylacetonate 

Relevant articles and documents

Synthesis method of tetraaryl nickel porphyrin catalyzed by anhydrous aluminum trichloride

The invention discloses a synthesis method of tetraaryl nickel porphyrin catalyzed by anhydrous aluminum trichloride, which comprises the following step: refluxing aromatic aldehyde, pyrrole and nickel salt in a DMF solvent under the catalysis of anhydrous aluminum trichloride to synthesize tetraaryl nickel porphyrin in one step. The reaction process comprises the following steps: sequentially adding anhydrous aluminum trichloride, aryl aldehyde, pyrrole and nickel salt into DMF (Dimethyl Formamide) while stirring, stopping the reaction after heating reflux reaction for a certain time, cooling, standing overnight near 273K, and carrying out suction filtration to obtain a nickel porphyrin crystal. According to the method, aromatic aldehyde, pyrrole and nickel salt are directly used as raw materials, porphin is not needed, strongly corrosive organic acid is not used as a solvent, high-purity tetraaryl nickel porphyrin is obtained at a high yield under the condition that a complex separation means is not needed, and industrial production is easy to achieve.