58246-76-7Relevant articles and documents
Nano rod-shaped and reusable basic Al2O3 catalyst for N-formylation of amines under solvent-free conditions: A novel, practical and convenient 'NOSE' approach
Das, Vijay Kumar,Devi, Rashmi Rekha,Raul, Prasanta Kumar,Thakur, Ashim Jyoti
supporting information; experimental part, p. 847 - 854 (2012/04/23)
An expeditious, simple, highly efficient, practical and green protocol for the N-formylation of alkyl/aryl amines and indole derivatives catalyzed by novel nano rod-shaped basic Al2O3 under solvent-free conditions has been developed. The catalyst is efficiently recycled up to the 5th run, an important point in the domain of green chemistry. The methodology provides cleaner conversion, shorter reaction times and high selectivity which makes the protocol attractive. The Royal Society of Chemistry 2012.
Pd/C-catalyzed reductive formylation of indoles and quinolines using formic acid
Kulkarni, Aditya,Gianatassio, Ryan,Toeroek, Bela
scheme or table, p. 1227 - 1232 (2011/05/14)
A two-step, one-pot domino reaction methodology was developed to synthesize a variety of N-formylindolines and N-formyltetrahydroquinolines from the corresponding indoles and quinolines. In the first step, the heterocyclic compounds are reduced to the corresponding dihydro or tetrahydro products by a Pd/C-catalyzed transfer hydrogenation using formic acid as a hydrogen donor. In the second step, nitrogen is formylated by formic acid to afford the final products in very good isolated yields. Georg Thieme Verlag Stuttgart New York.
PHASE-TRANSFER CATALYZED PERMANGANTE OXIDATIONS USING TRISAMINE (TDA-1)
McKillop, Alexander,Mills, Lester S.
, p. 647 - 656 (2007/10/02)
Oxidation of arylmethanols with KMnO4/TDA-1 under phase-transfer conditions at room temperature gives good to excellent yields of benzaldehydes.A number of other functional groups are also oxidised efficiently with the same reagent system.
