58285-79-3

Basic information

• Product Name: 2-methoxy-4-(((4-methoxyphenyl)amino)methyl)phenol
• CAS NO: 58285-79-3
• Molecular Weight: 259.305
• Mol File: 58285-79-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-methoxy-4-(((4-methoxyphenyl)amino)methyl)phenol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methoxy-4-(((4-methoxyphenyl)amino)methyl)phenol(58285-79-3)
• EPA Substance Registry System: 2-methoxy-4-(((4-methoxyphenyl)amino)methyl)phenol(58285-79-3)

Safety Data

• Hazardous Substances Data: 58285-79-3(Hazardous Substances Data)

Upstream product

• 104-94-9 4-methoxy-aniline 
• 3391-75-1 2-methoxy-4-((E)-phenylethenyl)phenol 
• 2101-87-3 p-methoxy-phenylazide 
• 121-33-5 vanillin 
• 24033-07-6 4-methoxy-N-(4-hydroxy-3-methoxybenzylidene)aniline 

Downstream Products

• 1401204-98-5 C₂₂H₂₂N₂O₄ 
• 1401205-09-1 C₂₂H₂₂N₂O₃S 

Relevant articles and documents

Iron-Catalyzed Nitrene Transfer Reaction of 4-Hydroxystilbenes with Aryl Azides: Synthesis of Imines via C=C Bond Cleavage

C=C bond breaking to access the C=N bond remains an underdeveloped area. A new protocol for C=C bond cleavage of alkenes under nonoxidative conditions to produce imines via an iron-catalyzed nitrene transfer reaction of 4-hydroxystilbenes with aryl azides is reported. The success of various sequential one-pot reactions reveals that the good compatibility of this method makes it very attractive for synthetic applications. On the basis of experimental observations, a plausible reaction mechanism is also proposed.