58296-98-3

Basic information

• Product Name: Benzaldehyde, 3-methoxy-, dimethylhydrazone
• CAS NO: 58296-98-3
• Molecular Formula: C10H14N2O
• Molecular Weight: 178.234
• Mol File: 58296-98-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzaldehyde, 3-methoxy-, dimethylhydrazone(CAS DataBase Reference)
• NIST Chemistry Reference: Benzaldehyde, 3-methoxy-, dimethylhydrazone(58296-98-3)
• EPA Substance Registry System: Benzaldehyde, 3-methoxy-, dimethylhydrazone(58296-98-3)

Safety Data

• Hazardous Substances Data: 58296-98-3(Hazardous Substances Data)

Upstream product

• 684-26-4 N,N-dimethyl-N',N'-bis(trimethylsilyl)hydrazine 
• 591-31-1 3-methoxy-benzaldehyde 
• 123767-44-2 3-methoxylbenzyl azide 
• 57-14-7 N,N-Dimethylhydrazine 

Downstream Products

• 1527-89-5 3-methoxybenzonitrile 
• 5813-86-5 m-methoxybenzamide 
• 586-38-9 3-Methoxybenzoic acid 

Relevant articles and documents

Hydrazone as the directing group for Ir-catalyzed arene diborylations and sequential functionalizations

The use of hemilabile pyridine-hydrazone N,N-ligands allows the highly selective Ir-catalyzed ortho,ortho'-directed diborylation of aromatic N,N-dimethylhydrazones in near-quantitative yields. One-pot sequential Suzuki-Miyaura cross-coupling with different aryl bromides provides a short entry to unsymmetrically substituted 2,6-diarylbenzaldehyde derivatives.

COUNTERATTACK REAGENTS: HEXAMETHYLDISILANE AND 1,2-DIMETHYL-1,1,2,2-TETRAPHENYLDISILANE IN THE SYNTHESIS OF POLYSILYLATED HYDRAZINES

Polysilylated hydrazines have wide applicability.It is tedious to prepare these compounds by classic means.However, using hexamethyldisilane and 1,2-dimethyl-1,1,2,2-tetraphenyldisilane as counterattack reagents, we synthesized polysilylated hydrazines under alkaline conditions in good to excellent yields.This one-pot method is expedient and more efficient than other procedures.Polysilylated hydrazines were found to react with aldehydes or ketones in the presence of a catalytic amount of trimethylsilyl trifluoromethanesulfonate to give the corresponding hydrazones under anhydrous conditions.