5831-43-6Relevant articles and documents
Simple Modifications for the Facile Preparation of 1,1,2,3,4,4-Hexaaryl-1,3-butadienes
Sakaguchi, Tomoya,Kusumoto, Naoki,Shimomura, Osamu,Ohtaka, Atsushi
, (2022/01/11)
A facile preparation of 1,1,2,3,4,4-hexaaryl-1,3-butadienes which are important molecules due to their aggregation-induced emission (AIE) activity was achieved by simple modifications of the reaction conditions reported in the previous work. In this react
1, 1, 2, 2 - Tetraborate ethylene, and preparation method and application thereof (by machine translation)
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Paragraph 0052-0056, (2019/10/01)
The invention discloses 1, 1, 2, 2 - tetraborate ethylene and a preparation method and application, 1, 1, 2, 2 - tetraborate ethylene, and the structural formula thereof is: Where. 1, 1, 2, 2 - Tetraborate ethylene and halogenated aromatic hydrocarbon are
Tetraarylethylenes from Diarylmethanones and Hexachlorodisilane: The “Sila-McMurry” Reaction
Moxter, Maximilian,Tillmann, Jan,Füser, Matthias,Bolte, Michael,Lerner, Hans-Wolfram,Wagner, Matthias
supporting information, p. 16028 - 16031 (2016/10/26)
Hexachlorodisilane reacts with diarylmethanones (aryl=C6H5, 4-MeC6H4, 4-tBuC6H4, 4-ClC6H4, 4-BrC6H4) to furnish the corresponding tetraarylethylenes in good yields. The reductive conversion requires temperatures of about 160 °C and reaction times of 60–72 h. In the initial step, the Lewis-basic carbonyl groups likely generate low-valent [SiCl2] as an analogue of [TiCl2] in the classical McMurry reaction. The coupling sequence further proceeds via benzopinacolones, which have been isolated as key intermediates.