58491-62-6Relevant articles and documents
Catalytic Amidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxamide over Alkali Manganese Oxides
Li, Xiaofang,Jia, Xiuquan,Ma, Jiping,Xu, Yongming,Huang, Yizheng,Xu, Jie
, p. 984 - 990 (2017)
2,5-Furandicarboxamide was firstly synthesized in yield of 85% via catalytic oxidative amidation of 5-hydroxymethylfurfural with aqueous NH3 over alkali manganese oxides of α-MnO2/NaxMnO2. The intermediates of 5-hydroxymethyl-furonitrile, 2,5-dicyanofuran, and 5-cyano-2-furancarboxamide were verified and their reactivities were further examined. The kinetic analysis results showed that the transformation of intermediate product of 5-cyano-2-furancarboxamide to 2,5-furan-dicarboxamide is a slower step, which is closely relative to the reaction temperature and basicity of catalyst.
Method for continuous preparation of nitriles in a pipelined reactor (by machine translation)
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Paragraph 0036-0047; 0056; 0058, (2020/12/14)
The method comprises the following steps that a tin catalyst is coated on the inner wall of the pipeline reactor; and the method comprises the following steps: coating a tin catalyst on the inner wall of the pipeline reactor. The amide solution and the catalytic auxiliary agent are mixed and then sent to a pipeline reactor, and the amide is dehydrated to generate nitrile at the reaction pressure of 0.1 - 2.0 mpa and 100 - 200 °C reaction temperature. The resulting reaction product was separated to give the crude product of the nitrile to which the amide corresponded. In the pipeline reactor, the corresponding nitrile is continuously prepared under the action of the tin catalyst, a dehydrating agent is not needed, byproducts only are water, and three wastes are reduced. (by machine translation)
Preparation method of 2, 5-dicyanofuran
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Paragraph 0049-0080, (2020/11/05)
The invention discloses a preparation method of 2, 5-dicyanofuran, and the method comprises the following steps: in the presence of an oxidant, reacting a mixture containing 2, 5-diformyl furan, a nitrogen source and a catalyst to obtain the 2, 5-dicyanofuran, wherein the catalyst comprises a metal oxide modified by an organic compound. According to the method for preparing the 2, 5-dicyanofuran through efficient catalytic ammoxidation of the 2, 5-diformyl furan provided by the invention, high-quality 2, 5-dicyanofuran is prepared through high-selectivity ammoxidation of the 2, 5-diformyl furan under mild conditions. The method is high in oxidation efficiency and high in product yield; air or oxygen serves as an oxygen source, ammonium salt serves as the nitrogen source, and the nitrogen source is high in utilization rate, clean and environment-friendly; the product and the catalyst are easy to separate, the post-treatment is simple, and the application prospect is good.