58647-73-7

Basic information

• Product Name: 2-[(4-methoxyphenyl)methyl]cyclopentanone
• Synonyms: 2-[(4-methoxyphenyl)methyl]cyclopentanone
• CAS NO: 58647-73-7
• Molecular Weight: 204.269
• Mol File: 58647-73-7.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 2-[(4-methoxyphenyl)methyl]cyclopentanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-[(4-methoxyphenyl)methyl]cyclopentanone(58647-73-7)
• EPA Substance Registry System: 2-[(4-methoxyphenyl)methyl]cyclopentanone(58647-73-7)

Safety Data

• Hazardous Substances Data: 58647-73-7(Hazardous Substances Data)

Upstream product

• 104-92-7 1-bromo-4-methoxy-benzene 
• 104-21-2 p-methoxybenzyl acetate 
• 19980-43-9 1-(trimethylsilyloxy)cyclopentene 
• 105-13-5 4-Methoxybenzyl alcohol 
• 5405-95-8 4,4'-dimethoxydibenzyl ether 
• 824-94-2 p-methoxybenzyl chloride 
• 25786-65-6 1-(4-methoxy-benzyl)-2-oxo-cyclopentanecarboxylic acid ethyl ester 
• 120-92-3 cyclopentanone 
• 7148-07-4 1-pyrrolidinocyclopent-1-ene 
• 412027-46-4 2-(4-methoxy-benzyl)-adipic acid 
• 108-24-7 acetic anhydride 
• 123-11-5 4-methoxy-benzaldehyde 

Downstream Products

• 158096-72-1 ethyl N-(2-<4-(2-oxocyclopent-1-ylmethyl)phenoxy>ethyl)carbamate 
• 158096-93-6 ethyl 2-<4-(2-oxocyclopent-1-ylmethyl)phenoxy>ethyl carbonate 
• 120647-36-1 2-(4-hydroxybenzyl)cyclopentan-1-one ethylene acetal 
• 84715-32-2 2-(4-hydroxybenzyl)cyclopentan-1-one 
• 73403-12-0 2-(4-Methoxy-benzyl)-2,5,5-trimethyl-cyclopentanone 
• 336884-10-7 tetrahydro-6-[(4-methoxyphenyl)methyl]-2H-pyran-2-one 

Relevant articles and documents

Palladium-catalyzed cross-coupling of cyclopropanol-derived ketone homoenolates with aryl bromides

The cross-coupling reaction of cyclopropanol-derived ketone homoenolates bearing β-hydrogens with aryl and hetaryl bromides has been achieved for the first time. This reaction is high yielding, is broad in scope and uses a simple catalytic system. Notably, the proposed palladium homoenolates do not undergo β-hydride elimination to the corresponding α,β- unsaturated ketones.

Chemo- and diastereoselective Bi(OTf)3-catalyzed benzylation of silyl nucleophiles

The direct alkylation of silyl enol ethers with para-methoxybenzylic alcohols or their corresponding acetates was efficiently catalyzed by Bi(OTf)3 in CH3NO2 as the solvent. The reaction provided the α-benzylated carbonyl

Tandem hemiketal formation-intramolecular Friedel-Crafts alkylation: A facile route to hetero-atom-substituted benzo-fused bicyclo[3.3.1]nonanes

A previously unknown intramolecular Friedel-Crafts alkylation with in situ formed hemiketals as the electrophile is reported.