586952-09-2

Basic information

• Product Name: 2-Butenoic acid, 4-hydroxy-, phenylmethyl ester, (2E)-
• CAS NO: 586952-09-2
• Molecular Formula: C11H12O3
• Molecular Weight: 192.214
• Mol File: 586952-09-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2-Butenoic acid, 4-hydroxy-, phenylmethyl ester, (2E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Butenoic acid, 4-hydroxy-, phenylmethyl ester, (2E)-(586952-09-2)
• EPA Substance Registry System: 2-Butenoic acid, 4-hydroxy-, phenylmethyl ester, (2E)-(586952-09-2)

Safety Data

• Hazardous Substances Data: 586952-09-2(Hazardous Substances Data)

Upstream product

• 110652-75-0 rac-2-oxiraneacetic acid phenylmethyl ester 
• 501-53-1 benzyl chloroformate 
• 23147-58-2 glycolaldehyde dimer 
• 15097-38-8 (carbobenzyloxymethylene)triphenylphosphorane 
• 86170-45-8 benzyl 3-butenoate 

Downstream Products

• 586952-15-0 benzyl (E)-4-p-toluenesulfonylaminocarbonyloxy-2-butenoate 
• 16504-57-7 (S)-3-amino-4-hydroxybutanoic acid 
• 586952-21-8 benzyl (3-p-toluenesulfonyl-1,3-oxazolidin-2-on-4-yl)acetate 

Relevant articles and documents

Ru(II)-Pheox-catalyzed asymmetric intramolecular cyclopropanation of electron-deficient olefins

The first highly enantioselective intramolecular cyclopropanation of electron-deficient olefins, in the presence of Ru(II) - Pheox catalyst, is reported. The corresponding cyclopropane-fused γ-lactones were obtained in high yields (up to 99%) with excelle

Stereoselective preparation of 3-alkanoylprop-2-en-1-ol derivatives

3-Alkanoylprop-2-en-1-ol derivatives were prepared stereoselectively by ring-opening reaction of β,γ-epoxyketone with amines. Georg Thieme Verlag Stuttgart.

Stereoselective synthesis of trans-4,5-disubstituted oxazolidin-2-ones by intramolecular conjugate addition of N-p-toluenesulfonyl carbamates

p-Toluenesulfonyl carbamates (2a-d) were prepared starting from allylic alcohols (3), in which the double bond is conjugated with an electron withdrawing group. In the presence of a catalytic amount of DBU, an intramolecular cyclisation occurred, leading