58735-67-4Relevant articles and documents
Self-assembly of a confined rhodium catalyst for asymmetric hydroformylation of unfunctionalized internal alkenes
Gadzikwa, Tendai,Bellini, Rosalba,Dekker, Henk L.,Reek, Joost N. H.
supporting information; experimental part, p. 2860 - 2863 (2012/03/26)
A chiral supramolecular ligand has been assembled and applied to the rhodium-catalyzed asymmetric hydroformylation of unfunctionalized internal alkenes. Spatial confinement of the metal center within a chiral pocket results in reversed regioselectivity and remarkable enantioselectivities.