587869-87-2

Basic information

• Product Name: (5Z)-7-{(1RS,2SR,5RS)-2-[(1E,3SR)-3-(tert-butyldimethylsilanyloxy)oct-1-enyl]-5-(2-nitrophenylselanyl)cyclopent-3-enyl}hept-5-enoic acid methyl ester
• Synonyms: (5Z)-7-{(1RS,2SR,5RS)-2-[(1E,3SR)-3-(tert-butyldimethylsilanyloxy)oct-1-enyl]-5-(2-nitrophenylselanyl)cyclopent-3-enyl}hept-5-enoic acid methyl ester
• CAS NO: 587869-87-2
• Molecular Weight: 648.817
• Mol File: 587869-87-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (5Z)-7-{(1RS,2SR,5RS)-2-[(1E,3SR)-3-(tert-butyldimethylsilanyloxy)oct-1-enyl]-5-(2-nitrophenylselanyl)cyclopent-3-enyl}hept-5-enoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (5Z)-7-{(1RS,2SR,5RS)-2-[(1E,3SR)-3-(tert-butyldimethylsilanyloxy)oct-1-enyl]-5-(2-nitrophenylselanyl)cyclopent-3-enyl}hept-5-enoic acid methyl ester(587869-87-2)
• EPA Substance Registry System: (5Z)-7-{(1RS,2SR,5RS)-2-[(1E,3SR)-3-(tert-butyldimethylsilanyloxy)oct-1-enyl]-5-(2-nitrophenylselanyl)cyclopent-3-enyl}hept-5-enoic acid methyl ester(587869-87-2)

Safety Data

• Hazardous Substances Data: 587869-87-2(Hazardous Substances Data)

Upstream product

• 587869-81-6 (3aR,4R,5R,6aS)-benzoic acid 4-[(1E,3S)-3-(tert-butyl-dimethylsilanyloxy)-oct-1-enyl]-2-oxo-hexahydro-cyclopenta[b]furan-5-yl ester 
• 587869-85-0 (5Z)-7-{(1R,2R,5S)-2-[(1E,3S)-3-(tert-butyl-dimethylsilanyloxy)-oct-1-enyl]-5-hydroxy-cyclopent-3-enyl}-hept-5-enoic acid 
• 137563-95-2 (3aR,4R,5R,6aS)-4-[(1E,3S)-3-(tert-butyl-dimethylsilanyloxy)-oct-1-enyl]-5-hydroxy-hexahydro-cyclopenta[b]furan-2-one 
• 1010074-85-7 (3aR,4R,5R,6aS)-benzoic acid 4-[(1E)-3-hydroxy-oct-1-enyl]-2-oxo-hexahydro-cyclopenta[b]furan-5-yl ester 
• 587869-91-8 (3aR,4S,6aS)-4-[(1E,3S)-3-(tert-butyl-dimethylsilanyloxy)-oct-1-enyl]-3,3a,4,6a-tetrahydro-2H-cyclopenta[b]furan-2-ol 
• 40834-86-4 (3aR,4R,5R,6aS)-benzoic acid 2-oxo-4-[(1E)-3-oxo-oct-1-enyl]-hexahydro-cyclopenta[b]furan-5-yl ester 
• 39746-01-5 (1S,5R,6R,7R)-6-formyl-7-benzoyloxy-2-oxabicyclo[3.3.0]octan-3-one 
• 87727-92-2 (3aR,4R,6aS)-4-[(1E,3S)-3-(tert-butyl-dimethylsilanyloxy)-oct-1-enyl]-3,3a,4,6a-tetrahydro-cyclopenta[b]furan-2-one 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 17814-85-6 (4-carboxybutyl)triphenylphosphonium bromide 
• 51694-22-5 ortho-nitrophenyl selenocyanate 
• 587869-79-2 (5Z)-7-{(1R,2R,5S)-2-[(1E,3S)-3-(tert-butyl-dimethylsilanyloxy)-oct-1-enyl]-5-hydroxy-cyclopent-3-enyl}-hept-5-enoic acid methyl ester 

Downstream Products

• 60203-57-8 prostaglandin J₂ 

Relevant articles and documents

A → J prostaglandin swap: A new tactic for cyclopentenone prostaglandin synthesis

A practical methodology for the synthesis of J-type prostaglandins has been developed starting from the well-consolidated approaches established for the synthesis of A-type prostaglandins. An efficient 1,3-allylic transposition of the C-9 hydroxyl group o