58808-71-2Relevant articles and documents
A recyclable biphasic system for stereoselective and easily handled hydrochalcogenations
Tidei, Caterina,Sancineto, Luca,Bagnoli, Luana,Battistelli, Benedetta,Marini, Francesca,Santi, Claudio
supporting information, p. 5968 - 5975 (2015/03/30)
Vinyl selenides and vinyl sulfides were prepared by hydrochalcogenation of alkynes with selenols and thiols generated in situ by the reduction of the corresponding diselenides and disulfides with elemental zinc in a biphasic acidic medium. The yields, ste
Reaction of Benzenesulphenyl Chloride with α, β-Unsaturated Compounds: Part I - Reactions with Methyl Crotonate and Methyl Cinnamate in Presence of Pyridine
Bhongle, N. N.,Gogte, V. N.,Vankar, Y. D.
, p. 724 - 728 (2007/10/02)
Reaction of benzenesulphenyl chloride (PhSCl) with α, β-unsaturated systems, in the presence of pyridine, offers a convenient route to sulphenylate regiospecifically the α-position of such systems.The specific role of pyridine and the product analysis have been examined and rationalised on the basis of the formation of pyridine-assisted carbanion intermediates and the structure/stability of these carbanions.