58879-27-9

Basic information

• Product Name: Phosphonic acid, (3-chlorobenzoyl)-, dimethyl ester
• CAS NO: 58879-27-9
• Molecular Formula: C9H10ClO4P
• Molecular Weight: 248.603
• Mol File: 58879-27-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Phosphonic acid, (3-chlorobenzoyl)-, dimethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphonic acid, (3-chlorobenzoyl)-, dimethyl ester(58879-27-9)
• EPA Substance Registry System: Phosphonic acid, (3-chlorobenzoyl)-, dimethyl ester(58879-27-9)

Safety Data

• Hazardous Substances Data: 58879-27-9(Hazardous Substances Data)

Upstream product

• 618-46-2 m-Chlorobenzoyl chloride 
• 121-45-9 phosphorous acid trimethyl ester 

Downstream Products

• 1307916-00-2 dimethyl (3-chlorophenyl)bis(1-methyl-1H-indol-3-yl)methylphosphonate 
• 1307915-96-3 C₂₅H₂₂ClN₂O₃P 
• 1293917-93-7 dimethyl (2-(3-chlorophenyl)-4-oxo-3,4-dihydro-2H-pyran-2-yl)phosphonate 
• 89187-51-9 [(3-Chloro-phenyl)-(dimethoxy-phosphoryloxy)-methyl]-phosphonic acid dimethyl ester 
• 108-42-9 3-chloro-aniline 
• 139-71-9 m-chloroformanilide 
• 76387-51-4 Phosphorsaeure-1-(3-chlorphenyl)vinyl-dimethylester 
• 1599441-52-7 1-(dimethylphosphono)-1,2-bis(3-chlorophenyl)-2-oxoethyl dimethyl phosphate 
• 1315552-57-8 (R)-dimethyl [1-(3-chlorophenyl)-1-hydroxy-3-oxopropyl]phosphonate 
• 1307916-31-9 dimethyl 1-(3-chlorophenyl)-1-hydroxypropylphosphonate 
• 401824-09-7 dimethyl (1-(3-chlorophenyl)-1-hydroxyethyl)phosphonate 

Relevant articles and documents

Geminal difunctionalization of α-diazo arylmethylphosphonates: Synthesis of fluorinated phosphonates

A general approach towards diverse fluorinated phosphonates via geminal difunctionalization reactions of α-diazo arylmethylphosphonates is described. The diazo functionality (RR′CN2) is successfully converted to RR′CF2, RR′CHF, RR′CFBr or RR′CFNR′′2 groups by employing different fluorination reagents. A variety of fluorinated organophosphorus compounds were readily accessed in good to excellent yields from a common type of precursor.

Reactions of acyl phosphonates with organoaluminum reagents: A new method for the synthesis of secondary and tertiary α-hydroxy phosphonates

The reactions of organoaluminum reagents (trimethylaluminum, triethylaluminum, etc.) with aryl and alkyl acyl phosphonates, which lead to the formation of α-hydroxy phosphonates in moderate to good yields, are reported. This method provides easy access to

Novel Synthetic Aspects of the Phosphonate-Phosphate-Rearrangement. II. Synthesis of Enolphosphates from 1-Oxoalkanphosphonates and Sulfur-Ylides

Acylphosphonates 1 react with Sulfur-ylides 2 to give enolphosphates 3 and phosphonophosphates 4.The product ratio of 3 and 4 is determined by the substituent R3.If R3 is not electronwithdrawing the phosphonophosphate 4 is the sole reaction product. - Keywords: Acylphosphonates, behaviour towards S-ylides; Rearrangement of α-hydroxyphosphonates