58898-32-1

Basic information

• Product Name: 2-bromo-3-methylcyclohept-2-en-1-one
• CAS NO: 58898-32-1
• Molecular Weight: 203.079
• Mol File: 58898-32-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-bromo-3-methylcyclohept-2-en-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 2-bromo-3-methylcyclohept-2-en-1-one(58898-32-1)
• EPA Substance Registry System: 2-bromo-3-methylcyclohept-2-en-1-one(58898-32-1)

Safety Data

• Hazardous Substances Data: 58898-32-1(Hazardous Substances Data)

Upstream product

• 14525-83-8 3-methylcyclohept-2-en-1-one 
• 58898-34-3 (7,7-Dibromo-6-methyl-bicyclo[4.1.0]hept-1-yloxy)-trimethyl-silane 

Relevant articles and documents

Copper-Catalyzed Enantioselective 1,2-Reduction of Cycloalkenones

We report an asymmetric 1,2-reduction of cyclic α,β-unsaturated ketones to access various enantiomerically enriched cyclic allylic alcohols under mild conditions, catalyzed by in situ generated copper hydride ligated with (R)-DTBM-C3*-TunePhos. α-Brominated cycloalkenones were reduced with excellent enantioselectivities of up to 98% ee, while substrates that were without α-substituents were reduced chemoselectively, with moderate enantioselectivities.