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59059-44-8

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59059-44-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 59059-44-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,9,0,5 and 9 respectively; the second part has 2 digits, 4 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 59059-44:
(7*5)+(6*9)+(5*0)+(4*5)+(3*9)+(2*4)+(1*4)=148
148 % 10 = 8
So 59059-44-8 is a valid CAS Registry Number.

59059-44-8Relevant articles and documents

Radical condensation between benzylic alcohols and acetamides to form 3-arylpropanamides

Azizi, Kobra,Madsen, Robert

, p. 7800 - 7806 (2020/08/14)

A new radical condensation reaction is developed where benzylic alcohols and acetamides are coupled to generate 3-arylpropanamides with water as the only byproduct. The transformation is performed with potassium tert-butoxide as the only additive and gives rise to a variety of 3-arylpropanamides in good yields. The mechanism has been investigated experimentally with labelled substrates, trapping experiments and spectroscopic measurements. The findings indicate a radical pathway where potassium tert-butoxide is believed to serve a dual role as both base and radical initiator. The radical anion of the benzylic alcohol is proposed as the key intermediate, which undergoes coupling with the enolate of the amide to form the new C-C bond. Subsequent elimination to the corresponding cinnamamide and olefin reduction then affords the 3-arylpropanamides.

Selective aerobic oxidation of alkyl aromatics on Bi2MoO6 nanoplates decorated with Pt nanoparticles under visible light irradiation

Zhang, Bao,Yang, Xiaojing,Li, Jun,Cheng, Gang

supporting information, p. 12194 - 12197 (2018/11/21)

Pt/Bi2MoO6 nanoplates are efficient photocatalysts for the selective oxidation of saturated C-H bonds in alkyl aromatics under visible light illumination using O2 as an oxidant. This study opens a new window for direct C-H functionalization through the photocatalytic method based on cheap Bi2MoO6 semiconductor materials.

EFFICIENT METHOD FOR THE PREPARATION OF SUBSTITUTED BENZALDEHYDES BY THE OXIDATION OF CYCLOOCTATETRAENE, CYCLOHEPTATRIENE AND THEIR DERIVATIVES BY MOLECULAR OXYGEN IN THE PRESENCE OF PALLADIUM COMPLEXES

Dzhemileva, G. A.,Odinokov, V. N.,Dzhemilev, U. M.

, p. 2165 - 2167 (2007/10/02)

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