59059-44-8Relevant articles and documents
Radical condensation between benzylic alcohols and acetamides to form 3-arylpropanamides
Azizi, Kobra,Madsen, Robert
, p. 7800 - 7806 (2020/08/14)
A new radical condensation reaction is developed where benzylic alcohols and acetamides are coupled to generate 3-arylpropanamides with water as the only byproduct. The transformation is performed with potassium tert-butoxide as the only additive and gives rise to a variety of 3-arylpropanamides in good yields. The mechanism has been investigated experimentally with labelled substrates, trapping experiments and spectroscopic measurements. The findings indicate a radical pathway where potassium tert-butoxide is believed to serve a dual role as both base and radical initiator. The radical anion of the benzylic alcohol is proposed as the key intermediate, which undergoes coupling with the enolate of the amide to form the new C-C bond. Subsequent elimination to the corresponding cinnamamide and olefin reduction then affords the 3-arylpropanamides.
Selective aerobic oxidation of alkyl aromatics on Bi2MoO6 nanoplates decorated with Pt nanoparticles under visible light irradiation
Zhang, Bao,Yang, Xiaojing,Li, Jun,Cheng, Gang
supporting information, p. 12194 - 12197 (2018/11/21)
Pt/Bi2MoO6 nanoplates are efficient photocatalysts for the selective oxidation of saturated C-H bonds in alkyl aromatics under visible light illumination using O2 as an oxidant. This study opens a new window for direct C-H functionalization through the photocatalytic method based on cheap Bi2MoO6 semiconductor materials.
EFFICIENT METHOD FOR THE PREPARATION OF SUBSTITUTED BENZALDEHYDES BY THE OXIDATION OF CYCLOOCTATETRAENE, CYCLOHEPTATRIENE AND THEIR DERIVATIVES BY MOLECULAR OXYGEN IN THE PRESENCE OF PALLADIUM COMPLEXES
Dzhemileva, G. A.,Odinokov, V. N.,Dzhemilev, U. M.
, p. 2165 - 2167 (2007/10/02)
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