59089-08-6

Basic information

• Product Name: Benzonitrile, 3-(2-phenylethenyl)-
• CAS NO: 59089-08-6
• Molecular Formula: C15H11N
• Molecular Weight: 205.259
• Mol File: 59089-08-6.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Benzonitrile, 3-(2-phenylethenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzonitrile, 3-(2-phenylethenyl)-(59089-08-6)
• EPA Substance Registry System: Benzonitrile, 3-(2-phenylethenyl)-(59089-08-6)

Safety Data

• Hazardous Substances Data: 59089-08-6(Hazardous Substances Data)

Upstream product

• 28188-41-2 m-(bromomethyl)benzonitrile 
• 3058-39-7 4-iodobenzonitrile 
• 536-74-3 phenylacetylene 
• 100-42-5 styrene 
• 6952-59-6 3-cyanobromobenzene 
• 591-50-4 iodobenzene 
• 74-85-1 ethene 
• 69113-59-3 3-iodobenzonitrile 
• 766-84-7 3-chloro-benzonitrile 
• 5338-96-5 3-cyanostyrene 

Downstream Products

• 56856-42-9 m-Cyanobenzil 
• 6136-62-5 3-benzoylbenzonitrile 
• 60766-55-4 C₁₅H₁₄N₂ 
• 1429770-10-4 C₁₅H₁₄N₂ 

Relevant articles and documents

Mechanically Strong Heterogeneous Catalysts via Immobilization of Powderous Catalysts to Porous Plastic Tablets

Main observation and conclusion: We describe a practical and general protocol for immobilization of heterogeneous catalysts to mechanically robust porous ultra-high molecular weight polyethylene tablets using inter-facial Lifshitz-van der Waals Interactions. Diverse types of powderous catalysts, including Cu, Pd/C, Pd/Al2O3, Pt/C, and Rh/C have been immobilized successfully. The immobilized catalysts are mechanistically robust towards stirring in solutions, and they worked well in diverse synthetic reactions. The immobilized catalyst tablets are easy to handle and reused. Moreover, the metal leaching of immobilized catalysts was reduced significantly.

A robust first-pass protocol for the heck-mizoroki reaction

The Heck-Mizoroki (HM) reaction is one of the most widely used C-C bond-forming methods of contemporary synthesis. Notwithstanding this, these reactions frequently require significant optimization before efficient transformations can be obtained. We describe here the results of a study that aimed to establish a generic experimental protocol for HM reactions which enables acceptable yields from first-pass experiments. The methodology utilizes readily available stable catalysts and can be applied to a broad range of coupling partners.

The continuous-flow synthesis of styrenes using ethylene in a palladium-catalysed heck cross-coupling reaction

We report a palladium-catalysed ethylene Heck reaction for the vinylation of aryl iodides using a tube-in-tube gas-liquid reactor. The flow process afforded various styrenes in short reaction times, employing moderate ethylene pressure. Georg Thieme Verlag Stuttgart · New York.