59117-56-5Relevant articles and documents
Molecular orbital studies on pericyclic reactions of cinnamyl xanthates in β-cyclodextrin cavities
Eto,Kubota,Nakagawa,Yoshitake,Harano
, p. 1652 - 1659 (2000)
The solid β-cyclodextrin (β-CyD) complex of O-cinnamyl S-methyl dithiocarbonates (xanthate, 1a), upon heating at 45°C, underwent asymmetric [3,3]-sigmatropic rearrangement to give the optically S-(1-phenylallyl) S-methyl dithiocarbonate (2a) with 60% ee.
Catalytic behavior of phenols in pyrolytic conversion of allylic dithiolcarbonates to allylic sulfides
Harano,Yamashiro,Misaka,Hisano
, p. 2956 - 2959 (2007/10/02)
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Homogenous Catalysis. Production of Allyl Alkyl Sulphides by Palladium Mediated Allylation
Auburn, Pamela R.,Whelan, John,Bosnich, B.
, p. 146 - 147 (2007/10/02)
The use of O-allyl S-alkyl dithiocarbonate substrates in palladium mediated catalytic allylation gives carbonyl sulphide and allyl alkyl sulphides with net retention of configuration and their use obviates the problems associated with sulphur nucleophiles in catalytic allylation.