59142-69-7Relevant articles and documents
Borylation of Olefin C-H Bond via Aryl to Vinyl Palladium 1,4-Migration
Hu, Tian-Jiao,Zhang, Ge,Chen, Ya-Heng,Feng, Chen-Guo,Lin, Guo-Qiang
supporting information, p. 2897 - 2900 (2016/03/19)
The aryl to vinyl palladium 1,4-migration was realized for the first time. The generated alkenyl palladium species was trapped by diboron reagents under Miyaura borylation conditions, providing a new method to synthesize β,β-disubstituted vinylboronates. The excellent regioselectivity and broad substrate scope were observed for this novel transformation.
Substituted 1,3-dihydrospiro(isobenzofuran)s
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, (2008/06/13)
Novel substituted 1,3-dihydrospiro[isobenzofuran]s and methods of preparing the same are described. These compounds are useful as antidepressants, tranquilizers, analgetic agents and intermediates therefor.