592489-19-5

Basic information

• Product Name: Benzenamine, N-(1,3-dimethyl-2-imidazolidinylidene)-4-(trifluoromethyl)-
• CAS NO: 592489-19-5
• Molecular Formula: C12H14F3N3
• Molecular Weight: 257.258
• Mol File: 592489-19-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzenamine, N-(1,3-dimethyl-2-imidazolidinylidene)-4-(trifluoromethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N-(1,3-dimethyl-2-imidazolidinylidene)-4-(trifluoromethyl)-(592489-19-5)
• EPA Substance Registry System: Benzenamine, N-(1,3-dimethyl-2-imidazolidinylidene)-4-(trifluoromethyl)-(592489-19-5)

Safety Data

• Hazardous Substances Data: 592489-19-5(Hazardous Substances Data)

Upstream product

• 592489-01-5 1,3-dimethyl-2-imidazolidinone O-(tetrahydropyran-2-yl)oxime 
• 42136-39-0 1,3-dimethyl-2-imidazolidinone oxime 
• 402-51-7 4-(trifluoromethyl)phenylmagnesium bromide 
• 592489-03-7 1,3-dimethyl-2-imidazolidinone O-p-tosyloxime 

Downstream Products

• 455-14-1 4-trifluoromethylphenylamine 
• 623-08-5 N-methyl-p-toluidine 
• 22864-65-9 N-methyl-4-(trifluoromethyl)aniline 
• 619-45-4 4-methoxycarbonyl aniline 

Relevant articles and documents

Synthesis of primary amines and N-methylamines by the electrophilic amination of Grignard reagents with 2-imidazolidinone O-sulfonyloxime

2-Imidazolidinone O-sulfonyloxime reacts with various aryl and alkyl Grignard reagents as an electrophilic amination reagent, giving N-alkylated imines. The resulting imines are transformed to primary amines and N-methyl secondary amines by hydrolysis with CsOH and LiAlH4 reduction, respectively.