5925-82-6 Usage
General Description
4-CHLOROBENZYL METHYL SULFIDE is a chemical compound with the molecular formula C8H9ClS. It is a sulfide compound with a chlorobenzyl group and a methyl group attached to a sulfur atom. This chemical is commonly used as an intermediate in organic synthesis and can also be found in some industrial processes. It is known for its distinct odor and is used in the production of certain chemicals and pharmaceutical substances. Additionally, 4-CHLOROBENZYL METHYL SULFIDE has been studied for its potential use in insect repellents and has shown efficacy against certain insect species. However, it is important to handle this compound with caution, as it may be harmful if ingested or inhaled.
Check Digit Verification of cas no
The CAS Registry Mumber 5925-82-6 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 5,9,2 and 5 respectively; the second part has 2 digits, 8 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 5925-82:
(6*5)+(5*9)+(4*2)+(3*5)+(2*8)+(1*2)=116
116 % 10 = 6
So 5925-82-6 is a valid CAS Registry Number.
InChI:InChI=1/C15H13FN2O3/c1-20-13-7-5-10(6-8-13)14(17)18-21-15(19)11-3-2-4-12(16)9-11/h2-9H,1H3,(H2,17,18)
5925-82-6Relevant articles and documents
Selective Methylation of Amides, N-Heterocycles, Thiols, and Alcohols with Tetramethylammonium Fluoride
Cheng, Hong-Gang,Pu, Maoping,Kundu, Gourab,Schoenebeck, Franziska
supporting information, p. 331 - 334 (2019/12/30)
We herein disclose the use of tetramethylammonium fluoride (TMAF) as a direct and selective methylating agent of a variety of amides, indoles, pyrroles, imidazoles, alcohols, and thiols. The method is characterized by operational simplicity, wide scope, and ease of purification. Our computational studies suggest a concerted methylation-deprotonation as the preferred reaction pathway.
Superelectrophilic methylthiomethylation of aromatics with chloromethyl methyl sulfide/aluminum chloride (MeSCH2Cl:2 AlCl3) reagent
Olah,Wang,Neyer
, p. 276 - 278 (2007/10/02)
Effective methylthiomethylation of aromatics was achieved by using chloromethyl methyl sulfide/aluminum chloride (MeSCH2Cl:2 AlCl3) as the alkylating agent. Excess aluminum chloride activates the thiocarboxonium ion intermediate by coordinating with sulfur and thus diminishes back donation of 'electron density' into the carbocationic center, rendering it a superelectrophilic methylthiomethylating agent.
