59527-14-9

Basic information

• Product Name: C₁₄H₁₂ClS
• CAS NO: 59527-14-9
• Molecular Weight: 247.768
• Mol File: 59527-14-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₄H₁₂ClS(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₄H₁₂ClS(59527-14-9)
• EPA Substance Registry System: C₁₄H₁₂ClS(59527-14-9)

Safety Data

• Hazardous Substances Data: 59527-14-9(Hazardous Substances Data)

Upstream product

• 1073-67-2 4-vinylbenzyl chloride 
• 4985-62-0 phenylthiyl 

Relevant articles and documents

Polar Effects in Addition Reactions of Benzenethiyl Radicals to Substituted Styrenes and α-Methylstyrenes Determined by Flash Photolysis

The absolute rate constants for the addition reactions of the benzenethiyl radical and its para-chloro derivative to para- and meta-substituted styrenes and α-methylstyrenes have been determined by the flash photolysis technique.The rate constants in the range of ca. 107-108 M-1 s-1 have been obtained.From the linear relationships in the Hammett plots vs. ?+, the reaction constants (ρ+) of C6H5S. toward substituted styrenes and α-methylstyrenes were estimated to be -0.26 and -0.30, respectively.The latter ρ+ value is compatible with the value estimated from the relative reactivities (-0.38).The polar effects of p-ClC6H4S. toward styrenes (ρ+ = -0.56) and α-methylstyrenes (ρ+ = -0.63) are larger that those of C6H4S..The sign and magnitudes of these ρ+ values are rationally interpreted in terms of the contribution of such polar resonance structure as -, CH2=C(R)C6H4Y+.> to the transition state.