59568-28-4 Usage
Description
BIS(TETRAMETHYLCYCLOPENTADIENYL)IRON, also known as Bis(tetramethylcyclopentadienyl)iron, is an organometallic compound with the chemical formula (C5H5)2Fe. It is a type of metallocene, which are organometallic compounds containing a metal atom bonded to cyclopentadienyl (Cp) ligands. BIS(TETRAMETHYLCYCLOPENTADIENYL)IRON is characterized by its unique chemical and electronic properties, making it a versatile compound with various applications in different industries.
Uses
Used in Paint and Coatings Industry:
BIS(TETRAMETHYLCYCLOPENTADIENYL)IRON is used as a catalyst for alkyd paint drying for its ability to mediate auto-oxidation reactions. This application enhances the curing process and improves the overall performance of the paint, leading to better durability and appearance.
Used in Photochemistry:
BIS(TETRAMETHYLCYCLOPENTADIENYL)IRON serves as an electron donor in photoinduced electron-transfer reduction reactions, which are controlled by conformational distortion. This property makes it a valuable component in the development of advanced photochemical processes and materials.
Used in Sensor Technology:
BIS(TETRAMETHYLCYCLOPENTADIENYL)IRON is employed as an electrocatalytical hydrogen peroxide and glucose sensor. Its sensitivity and selectivity in detecting these molecules make it a promising candidate for the development of efficient and accurate sensors in various applications, including medical diagnostics and environmental monitoring.
Used in Porphyrin Chemistry:
BIS(TETRAMETHYLCYCLOPENTADIENYL)IRON is utilized for interand intramolecular quenching of the lowest singlet excited state of porphyrins. This application is significant in the study and manipulation of porphyrin-based materials, which have potential uses in areas such as solar energy conversion, catalysis, and photodynamic therapy.
Check Digit Verification of cas no
The CAS Registry Mumber 59568-28-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,9,5,6 and 8 respectively; the second part has 2 digits, 2 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 59568-28:
(7*5)+(6*9)+(5*5)+(4*6)+(3*8)+(2*2)+(1*8)=174
174 % 10 = 4
So 59568-28-4 is a valid CAS Registry Number.
InChI:InChI=1/2C9H13.Fe/c2*1-6-5-7(2)9(4)8(6)3;/h2*5H,1-4H3;
59568-28-4Relevant articles and documents
1,1′-Diacetyloctamethylferrocene: An overlooked and overdue synthon leading to the facile synthesis of an octamethylferrocenophane
Roemer, Max,Skelton, Brian W.,Piggott, Matthew J.,Koutsantonis, George A.
, p. 18817 - 18821 (2016)
This paper describes the facile preparation of 1,1′-diacetyloctamethylferrocene (2) by acylation of octamethylferrocene (1) with acetyl chloride. Chloroformylation with POCl3/DMF of 2 affords a variety of products, including 1,1′-bis-(1-chlorovinyl)octamethylferrocene (3b) in high yield. Compound 3b cyclises in aqueous sodium hydroxide/DMF to an octamethyl[1,4]-ferrocenophane bearing a 1-dimethylaminobuta-1,3-diene-handle (4).
NMR Spectroscopy on Paramagnetic Complexes, XXVII. Paramagnetic 1,1',2,2',3,3',4,4'-Octamethylmetallocenes
Koehler, Frank H.,Doll, Karl H.
, p. 144 - 150 (2007/10/02)
The tetramethylated cyclopentadienyl anion has been prepared from tiglinic acid and reacted with solvated metal(II) chlorides to give new octamethylmetallocenes (Me4cp)2M.For M = V, Cr, Co and Ni the paramagnetic 1H and 13C spectra have been recorded.The NMR data prove the molecular structure and show that all methyl groups rotate almost freely.The methyl proton resonance of the nickelocene may serve as a probe for the adjustment of metallocene properties by ring substitution.Based on qualitative MO arguments the correlation of electron spin densities and paramagnetic shifts lead to an understanding of the signal splitting of cobaltocenes.From the electronic point of view the octamethylmetallocenes may be regarded as being invers to 1,1'-dimethylmetallocenes. - Key words: Octamethylmetallocenes, Paramagnetic 1H/13C NMR
