596087-20-6

Basic information

• Product Name: B-D-Glucopyranoside,4-methylphenyl6-O-[(1,1-dimethylethyl)diphenylsilyl]-2,3-bis-O-(phenylmethyl)-1-thio-
• Synonyms: B-D-Glucopyranoside,4-methylphenyl6-O-[(1,1-dimethylethyl)diphenylsilyl]-2,3-bis-O-(phenylmethyl)-1-thio-;Beta-D-Glucopyranoside,4-Methylphenyl6-O-[(1,1-diMethylethyl)diphenylsilyl]-2,3-bis-O-(phenylMethyl)-1-thio-
• CAS NO: 596087-20-6
• Molecular Formula: C₄₃H₄₈O₅SSi
• Molecular Weight: 704.98872
• Mol File: 596087-20-6.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: B-D-Glucopyranoside,4-methylphenyl6-O-[(1,1-dimethylethyl)diphenylsilyl]-2,3-bis-O-(phenylmethyl)-1-thio-(CAS DataBase Reference)
• NIST Chemistry Reference: B-D-Glucopyranoside,4-methylphenyl6-O-[(1,1-dimethylethyl)diphenylsilyl]-2,3-bis-O-(phenylmethyl)-1-thio-(596087-20-6)
• EPA Substance Registry System: B-D-Glucopyranoside,4-methylphenyl6-O-[(1,1-dimethylethyl)diphenylsilyl]-2,3-bis-O-(phenylmethyl)-1-thio-(596087-20-6)

Safety Data

• Hazardous Substances Data: 596087-20-6(Hazardous Substances Data)

Upstream product

• 1152-39-2 p-methylphenyl 1-thio-β-D-glucopyranoside 
• 850416-39-6 p-methylphenyl 2,3-di-O-benzyl-4,6-O-(R)-benzylidene-1-thio-β-D-glucopyranoside 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 596087-18-2 4-methylphenyl 2,3-di-O-benzyl-1-thio-β-D-glucopyranoside 
• 868241-49-0 (p-methylphenyl) 4,6-O-benzylidene-1-thio-β-D-glucopyranoside 

Downstream Products

• 918948-30-8 C₇₄H₇₃N₃O₁₁SSi 

Relevant articles and documents

Unusually Stable Picoloyl-Protected Trimethylsilyl Glycosides for Nonsymmetrical 1,1′-Glycosylation and Synthesis of 1,1′-Disaccharides with Diverse Configurations

Nonsymmetrical 1,1′-disaccharides and related derivatives constitute structural components in various glycolipids and natural products. Some of these compounds have been shown to exhibit appealing biological properties. We report a direct yet stereoselective 1,1′-glycosylation strategy for the synthesis of nonsymmetrical 1,1′-disaccharides with diverse configurations and sugar components. The strategy is based on the joined forces of a new class of configurationally stable glycoside acceptors and stereodirecting thioglycoside donors. The new glycoside acceptors feature a picoloyl (Pico) protecting group at the remote C4/C3 position that confers unusual stability on TMS glycosides under acidic conditions.

Synthesis of 48 disaccharide building blocks for the assembly of a heparin and heparan sulfate oligosaccharide library

(Chemical Equation Presented) An efficient synthesis of the entire set of suitably protected 48 disaccharide building blocks for the assembly of a heparin and heparan sulfate oligosaccharide library is described here.