59632-76-7 Usage
General Description
The chemical "(3aR,6E,10Z,14E,15aS)-2,3,3a,4,5,8,9,12,13,15a-Decahydro-6,14-dimethyl-3-methylene-2-oxocyclotetradeca[b]furan-10-carboxylic acid" is a complex molecule with a cyclical structure containing a carboxylic acid group. It has a total of 20 carbon atoms, arranged in a specific spatial configuration that gives it its unique properties. The presence of a double bond and a methyl group provides it with a high degree of reactivity, potentially making it useful in bioactive applications. Its structure also suggests potential for biological activity or pharmacological relevance. However, due to its complexity and the presence of reactive groups, it would require further investigation and analysis to fully understand its potential uses and effects.
Check Digit Verification of cas no
The CAS Registry Mumber 59632-76-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,9,6,3 and 2 respectively; the second part has 2 digits, 7 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 59632-76:
(7*5)+(6*9)+(5*6)+(4*3)+(3*2)+(2*7)+(1*6)=157
157 % 10 = 7
So 59632-76-7 is a valid CAS Registry Number.
InChI:InChI=1/C20H26O4/c1-13-6-4-8-16(19(21)22)9-5-7-14(2)12-18-17(11-10-13)15(3)20(23)24-18/h6,9,12,17-18H,3-5,7-8,10-11H2,1-2H3,(H,21,22)/b13-6+,14-12-,16-9-
59632-76-7Relevant articles and documents
CEMBRANOLIDE TOTAL SYNTHESIS. ANISOMELIC ACID
Marshall, James A.,DeHoff, Bradley S.
, p. 4849 - 4860 (2007/10/02)
The stereoselective total synthesis of (+/-)-anisomelic acid (34) has been achieved starting from aldehyde 7, the ozonolysis product of geranyl acetate.Two key steps ensured the stereoselectivity of the synthesis.The first entailed a highly anti-selective addition of the allyltitanium derived from carbamate 15 to aldehyde 5 affording the enol carbamate allylic alcohol 16.The second was a highly (Z)-selective Horner-Emmons cyclization of the derived phosphono ester aldehyde 25 leading to the conjugated ester 27.Further conversion led to the crystalline lactone 30 whose structure was confirmed through single crystal X-ray analysis.Equilibration of the conjugated double bond of 30 gave rise to a 1:1 mixture of the (Z) and (E) isomers.This result was foretold by molecular mechanics calculations.