59637-41-1

Basic information

• Product Name: 2-methyl-4-[(3-methyl-2-butenyl)oxy]but-1-ene
• Synonyms: 2-methyl-4-[(3-methyl-2-butenyl)oxy]but-1-ene;2-Methyl-4-[(3-methyl-2-butenyl)oxy]-1-butene;1-Butene, 2-methyl-4-((3-methyl-2-butenyl)oxy)-;2-Butene, 3-methyl-1-((3-methyl-3-buten-1-yl)oxy)-;Bis-gamma, gamma-dimethylallyl ether;Einecs 261-829-3
• CAS NO: 59637-41-1
• Molecular Formula: C₁₀H₁₈O
• Molecular Weight: 154.24932
• EINECS: 261-829-3
• Mol File: 59637-41-1.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 192.2°C at 760 mmHg
• Flash Point: 56.3°C
• Appearance: /
• Density: 0.819g/cm³
• Vapor Pressure: 0.689mmHg at 25°C
• Refractive Index: 1.439
• CAS DataBase Reference: 2-methyl-4-[(3-methyl-2-butenyl)oxy]but-1-ene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methyl-4-[(3-methyl-2-butenyl)oxy]but-1-ene(59637-41-1)
• EPA Substance Registry System: 2-methyl-4-[(3-methyl-2-butenyl)oxy]but-1-ene(59637-41-1)

Safety Data

• Hazardous Substances Data: 59637-41-1(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H18O/c1-9(2)5-7-11-8-6-10(3)4/h6H,1,5,7-8H2,2-4H3

Upstream product

• 556-82-1 3-methyl-2-buten-1-ol 
• 763-32-6 2-methyl-1-buten-4-ol 
• 115-18-4 2-methyl-3-buten-2-ol 

Downstream Products

• 763-32-6 2-methyl-1-buten-4-ol 
• 7779-06-8 3,7-dimethyl 3,6-octadien-1-ol 
• 13066-51-8 γ-geraniol 

Relevant articles and documents

Synthesis of 6-(poly)prenyl-substituted polyprenols and their phosphates

The 6-(poly)prenyl-substituted polyprenols 7, 9, 11, and 13 were synthesized: (1) 7 from 2-geranyl-farnesal and methyl 4-bromo-3-methyl-2- butenoate, (2) 9 from 2-prenyl-geranyl bromide and ethyl acetoacetate, via ketone 29, (3) 11 from ethyl acetoacetate, geranyl bromide, and (E)-1-t- butyldiphenylsiloxy-5-iodo-3-methyl-2-pentene, via β-keto ester 35, and (4) 13 from geraniol by acid catalyzed condensation. These highly branched polyprenols 7, 9, 11, and 13 were transformed into the corresponding disodium phosphates 8, 10, 12, and 14, respectively.