59682-83-6Relevant articles and documents
MECHANISM OF THE COPPER MEDIATED OXIDATION OF PRIMARY ALIPHATIC AMINES BY THE Cu0/O2/ACETIC ACID SYSTEM IN ACETONITRILE
Capdevielle, Patrice,Lavigne, Andre,Maumy, Michel
, p. 2835 - 2844 (2007/10/02)
Primary aliphatic amines are oxidized to aldehydes by the Cu0/O2/AcOH system in acetonitrile.Kinetic measurements, particularly deuterium isotope effects studies, give support to the existence of a Cu(III) strong oxidant intermediate species in contrast with the Cu(I)/O2/pyridine oxidant system in which Cu(II) has the major role.