59807-21-5

Basic information

• Product Name: Pyrimidine, 2-(methylthio)-4,6-diphenyl-
• CAS NO: 59807-21-5
• Molecular Formula: C17H14N2S
• Molecular Weight: 278.378
• Mol File: 59807-21-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Pyrimidine, 2-(methylthio)-4,6-diphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Pyrimidine, 2-(methylthio)-4,6-diphenyl-(59807-21-5)
• EPA Substance Registry System: Pyrimidine, 2-(methylthio)-4,6-diphenyl-(59807-21-5)

Safety Data

• Hazardous Substances Data: 59807-21-5(Hazardous Substances Data)

Upstream product

• 6299-25-8 4,6-Dichloro-2-(methylthio)pyrimidine 
• 98-80-6 phenylboronic acid 
• 614-47-1 1,3-diphenyl-propen-3-one 
• 1979-98-2 4,6-dihydroxy-2-methylmercaptopyrimidine 
• 56734-10-2 2-(methylsulfanyl)-4-phenylpyrimidine 
• 591-51-5 phenyllithium 
• 32079-26-8 4,6-diphenyl-5,6-dihydropyrimidine-2(1H)-thione 
• 77-78-1 dimethyl sulfate 
• 108-86-1 bromobenzene 
• 154499-78-2 2-methylthio-4,6-pyrimidinyl ditriflate 

Downstream Products

• 78509-13-4 4,6-bis-phenyl-2-(4'-methoxyphenyl)pyrimidine 
• 78509-14-5 2-Naphthalen-2-yl-4,6-diphenyl-pyrimidine 
• 135587-61-0 4,4',6,6'-tetraphenyl-2,2'-bipyrimidine 
• 3977-48-8 4,6-diphenylpyrimidine 
• 1266389-14-3 2-(N-carbazolyl)-4,6-diphenylpyrimidine 

Relevant articles and documents

White-light emission from a pyrimidine-carbazole conjugate with tunable phosphorescence-fluorescence dual emission and multicolor emission switching

A metal-free organic carbazole-pyrimidine dye exhibiting phosphorescence-fluorescence dual emission was developed into a white-light emission-switching system. The two crystal polymorphs obtained by breaking the molecular symmetry responded to the external stimuli of heating, vapor-fuming, and mechanical grinding, resulting in a tricolor switching system that includes white-light emission.

Pyrimidine-core extended π-systems: General synthesis and interesting fluorescent properties

We have developed a simple but powerful synthetic strategy that permits the assembly of π-systems onto a pyrimidine core in a programmable and diversity-oriented format. The nucleophilic addition of ArLi to 2-methylthiopyrimidine, followed by 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) oxidation, resulted in the production of 4-aryl-2-methylthiopyrimidines. The iterative reaction sequence then gave 4,6-diaryl-2-methylthiopyrimidines. The resulting adduct was further allowed to react with ArMgBr under the catalytic influence of NiCl2(dppe) to afford 2,4,6-triarylpyrimidines. By following this synthetic scheme, interesting pyrimidine-core π-systems were rapidly constructed in a programmable fashion. The successful discovery of a number of interesting fluorescent materials and properties (e.g., solvatofluorochromism) speaks well for the potential of our platform strategy in the development of functional organic materials. Copyright

Studies on Heterocyclic Compounds: Part III - 4,6-Disubstituted 5,6 Dihydro-2(1H)pyrimidinethiones

Several 4,6-disubstituted 2-(1H)-pyrimidinethiones (3) and the corresponding 5,6-dihydro derivatives (2) have been prepared by the action of chalcones (1) with thiourea and screened for their antifungal and antibacterial activities.