59816-85-2Relevant articles and documents
Catalytic enantioselective alkene aminohalogenation/cyclization involving atom transfer
Bovino, Michael T.,Chemler, Sherry R.
supporting information; scheme or table, p. 3923 - 3927 (2012/05/20)
Problem solved: The title reaction was used for the synthesis of chiral 2-bromo, chloro, and iodomethyl indolines and 2-iodomethyl pyrrolidines (see scheme). Stereocenter formation is believed to occur by enantioselective cis aminocupration and C-X bond formation is believed to occur by atom transfer. The ultility of the products as versatile synthetic intermediates was demonstrated, as was a radical cascade cyclization sequence. Copyright
Boron trifluoride-diethyl ether complex catalyzed aromatic amino-Claisen rearrangements
Anderson,Lai
, p. 1287 - 1290 (2007/10/02)
Boron trifluoride-diethyl ether complex (BF3 · OEt2) was demonstrated to be an efficient catalyst for the amino-Claisen rearrangements of various aromatic N-allylamines into the corresponding o-allylamines in moderate yields.
