60159-38-8

Basic information

• Product Name: 4-(tricyclo[3.3.1.1~3,7~]dec-1-yl)pyridine
• Synonyms: 4-(1-Adamantyl)pyridine
• CAS NO: 60159-38-8
• Molecular Formula: C₁₅H₁₉N
• Molecular Weight: 213.3181
• Mol File: 60159-38-8.mol
• Article Data: 14

Chemical Properties

• Boiling Point: 329.4°C at 760 mmHg
• Flash Point: 191.9°C
• Density: 1.113g/cm³
• Vapor Pressure: 0.00034mmHg at 25°C
• Refractive Index: 1.589
• CAS DataBase Reference: 4-(tricyclo[3.3.1.1~3,7~]dec-1-yl)pyridine(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(tricyclo[3.3.1.1~3,7~]dec-1-yl)pyridine(60159-38-8)
• EPA Substance Registry System: 4-(tricyclo[3.3.1.1~3,7~]dec-1-yl)pyridine(60159-38-8)

Safety Data

• Hazardous Substances Data: 60159-38-8(Hazardous Substances Data)

Upstream product

• 281-23-2 adamantane 
• 91233-19-1 1-(adamantane-1-carbonyloxy)pyridine-2(1H)-thione 
• 110-86-1 pyridine 
• 107264-20-0 diphenylmethanone O-(adamantane-1-carbonyl) oxime 

Relevant articles and documents

On the reduction of basic iron acetate: Isolation of ferrous specis mediating Gif-type oxidation of hydrocarbons

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The selective functionalization of saturated hydrocarbons. Part 46. An investigation of Udenfriend's system under Gif conditions

Under Gif conditions using ascorbic acid as reductant and oxygen as oxidant in pyridine, the selectivity for secondary hydrogen functionalization is exceptional. EDTA (ethylenediamine-tetra-acetic acid) is not needed as a ligand for iron.

The Fe(II)-Fe(IV) and Fe(III)-Fe(V) manifolds in an expanded world of gif chemistry

The species responsible for hydrocarbon activation and formation of alkyl chlorides in the Fe(II) and Fe(III)-H2O2 and tert-butyl hydroperoxide systems are identified. The importance of the Fe(II)-Fe(IV) manifold in providing a mechanism which permits the selective functionalization of saturated hydrocarbons by ionic trapping with chloride, azide, and other anions is made manifest. Comparison is made with the Fe(III)-Fe(V) manifold where ionic trapping is never seen.