60211-88-3Relevant articles and documents
REACTION OF OLEFINS WITH A MIXTURE OF IODINE AND MERCURY(II) THIOCYANATE. PREDOMINANT FORMATION OF vic-IODO(ISOTHIOCYANATO)ALKANES.
Watanabe,Uemura,Okano
, p. 2458 - 2462 (1983)
Treatment of olefins with a mixture of iodine and mercury(II) thiocyanate in benzene or diethyl ether gives vic-iodo(isothiocyanato)alkanes and vic-iodo(thiocyanato)alkanes in a high yield, the former being predominant. Similar results were obtained by us
Nitrosonium Ion Promoted Iodination and 1,2-Iodofunctionalization of Cyclohexene
Radner, Finn
, p. 902 - 907 (2007/10/02)
The promoting influence of NO+BF4- on the addition of I2 or 'I+Nu-' couples to cyclohexene (1) in the presence of O2 is described. 1-Acetoxy-2-iodocyclohexane is obtained in 89percent isolated yield from the reaction of I2, 1 and CH3COOH in CH2Cl2, and the corresponding methoxy- and acetamido-substituted iodocyclohexanes are obtained in 96 and 92percent yield, when methanol and acetonitrile, respectively, are added.Applications of the method to the synthesis of cis-1,2-cyclohexanediol (Woodward reaction) and bis(2-iodocyclohexyl) ether is described.
Supported Reagents in Facile and Selective Two-phase Additions to C=C Double Bonds
Ando, Takashi,Clark, James H.,Cork, David G.,Fujita, Mitsue,Kimura, Takahide
, p. 1301 - 1302 (2007/10/02)
Inorganic-solid-supported KSCN, NaN3, and KOAc mixed with iodine and an alkene in CHCl3 gave products by a facile two-phase addition.
