6040-30-8Relevant articles and documents
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Itokawa,H.,Nakajima,H.
, p. 2539 (1981)
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Enantioselective total synthesis of oleanolic acid, erythrodiol, β- amyrin, and other pentacyclic triterpenes from a common intermediate
Corey,Lee
, p. 8873 - 8874 (2007/10/02)
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Oxidative Decarboxylation: Partial Synthesis of Aegiceradienol (nor Echinocystadienol)
Sundararamaiah, T.,Rao, V. Vishwanath
, p. 74 - 76 (2007/10/02)
3β-Acetoxy olean-12-en-28-oic acid (III) (acetyl oleanolic acid) on oxidative decarboxylation with lead tetraacetate-cupric acetate gave a complex diene mixture (IV) which isomerised on heating with acetic acid-hydrochloric acid to 28-nor olean-12,17-dien-3 β-yl acetate (V) (aegiceradienyl acetate).Hydrolysis of the acetate gave 28-nor olean-12,17-dien-3β-ol(I) (aegiceradienol). 3-Oxo olean-12-en-28-oic acid (oleanonic acid) (VII) on oxidative decarboxylation gave 28-nor olean-12,17-dien-3-one (VI) which on reduction with sodium borohydride gave 28-nor olean-12,17-dien 3β-ol (aegiceradienol).