60414-82-6

Basic information

• Product Name: INDANE-1,3-DIOL
• Synonyms: 2,3-Dihydro-1H-indene-1,3-diol;1H-Indene-1,3-diol, 2,3-dihydro-
• CAS NO: 60414-82-6
• Molecular Formula: C₉H₁₀O₂
• Molecular Weight: 150.18
• Mol File: 60414-82-6.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 337.8±30.0 °C(Predicted)
• Appearance: /
• Density: 1.334±0.06 g/cm3(Predicted)
• PKA: 13.57±0.40(Predicted)
• CAS DataBase Reference: INDANE-1,3-DIOL(CAS DataBase Reference)
• NIST Chemistry Reference: INDANE-1,3-DIOL(60414-82-6)
• EPA Substance Registry System: INDANE-1,3-DIOL(60414-82-6)

Safety Data

• Hazardous Substances Data: 60414-82-6(Hazardous Substances Data)

Upstream product

• 26976-59-0 3-hydroxy-2,3-dihydro-1H-inden-1-one 
• 606-23-5 1H-indene-1,3(2H)-dione 
• 64-17-5 ethanol 
• 38846-64-9 2-ethynylbenzaldehyde 

Downstream Products

• 606-23-5 1H-indene-1,3(2H)-dione 
• 26976-59-0 3-hydroxy-2,3-dihydro-1H-inden-1-one 

Relevant articles and documents

Chemoselective formation of cyclo-aliphatic and cyclo-olefinic 1,3-diolsviapressure hydrogenation of potentially biobased platform molecules using Kn?lker-type catalysts

The hydrogenative conversions of the biobased platform molecules 4-hydroxycyclopent-2-enone and cyclopentane-1,3-dione to their corresponding 1,3-diols are established using a pre-activated Kn?lker-type iron catalyst. The catalyst exhibits a high selectivity for ketone reduction, and does not induce dehydration. Moreover, by using different substituents of the ligand, thecis-transratio of the products can be affected substantially. A decent compatibility of this catalytic system with various structurally related substrates is demonstrated.

A Method for Synthesis of 3-Hydroxy-1-indanones via Cu-Catalyzed Intramolecular Annulation Reactions

We report a facile and highly efficient method that copper-catalyzed intramolecular annulation to synthesize 3-hydroxy-1-indanones employing simple 2-ethynylbenzaldehyde as starting materials was achieved successfully. This protocol provided a simple synthetic approach to afford 3-hydroxy-1-indanones under mild conditions in good to excellent yields.

Facile reduction of aromatic aldehydes, ketones, diketones and oxo aldehydes to alcohols by an aqueous TiCl3/NH3 system: Selectivity and scope

A simple and rapid procedure for the almost quantitative reduction of aromatic aldehydes, ketones, diketones and oxo aldehydes to alcohols by use of TiCl3/NH3 in aqueous methanol solution is reported. The reducing system distinguishes between different classes of aldehydes and/or ketones, and many functionalities that usually do not survive under reducing conditions are tolerated well. The concept of reversal of chemoselectivity has also been developed. A mechanism based on two sequential one-electron transfers from TiIII to the carbonyl carbon atom is proposed, the second SET becoming operative only in the presence of ammonium ion (either added or formed in situ). Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002.